Synthesis of Functionalized Aryl-vinyl Ethers as Building Blocks and Auxiliaries in Organic Synthesis

Journal of Applied Chemical Research

مقاله 5، دوره 6، شماره 3، مهر 2012، صفحه 46-52   

نوع مقاله: Research Paper

نویسندگان

B. Mohtat^* ؛ L. Pirhadi؛ S. Azimzadeh؛ H. Djahaniani

چکیده

5- hydroxyisoquinoline undergoes a smooth reaction with alkyl propiolates in the presence of triphenylphosphine (15 mol%) to produce the corresponding (E)-alkyl 3-(isoquinolin-5-yloxy) acrylate in good yields. When the reaction was performed by 2-methyl 4-hydroxyquinoline and 3-nitro 4-hydroxypyridine, similar aryl vinyl ethers were obtained.

کلیدواژه‌ها

OH-acids؛ 5- hydroxyisoquinoline؛ 2-methyl 4-hydroxyquinoline؛ 3-nitro 4-hydroxypyridine؛ Aryl vinyl ethers؛ Alkyl propiolates؛ Triphenylphosphine