Volumetric properties of {n-butyl acetate + 1-butanol + 1,2- butanediol} at temperature between [298.15 ,303.15 and 308.15] K.

Journal of the Iranian Chemical Research

مقاله 4، دوره 3، شماره 4، اسفند 2010، صفحه 245-256   

نویسندگان

Saleh Bagheri^{* 1}؛ Mahdi Rakhshi²؛ Mahdi Rezaei Sameti³

¹Department of Physical and Theoretical Chemistry , Faculty of Chemistry, Islamic Azad University, Tehran North Branch, Tehran, Iran

²Faculty of Chemistry, University of Bu Ali Sina, Hamadan, Iran

³Department of Chemistry, Faculty of Science, Malayer University, Malayer, Iran

چکیده

Densities and excess molar volume of the binary and ternary mixtures formed by nbutylacetate
+ 1-butanol + 1,2-butanediol were measured at (298.15, 303.15, and 308.15) K for
the liquid region and at ambient pressure (81.5) k Pa , for the whole composition range. The
excess molar volumes,Vm
E and excess partial molar volume Vi
E ,were calculated from
experimental densities.The excess molar volumes are positive over the mole fraction rage for
binary mixtures of n-butylacetate (1) + 1-butanol (2) and n-butylacetate (2) + 1,2-butanediol (3)
and increase with increasing temperatures from (298.15 to 308.15)K. The excess molar volumes
of 1-butanol (1) + 1,2-butanediol (3) are negative and decrease with increasing temperatures
from (298.15 to 308.15)K..The experimental data of constitute were correlated as a function of
the mole fraction by using the Redlich–Kister equation for binary and , Cibulka, Jasinski and
Malanowski , Singe et al, Pintos et al , Calvo et al, Kohler, and Jacob - Fitzner for ternary
mixture ,respectively. The experimental data of the constitute binaries are analyzed to discuss the
nature and strength of intermolecular interactions in these mixtures.

کلیدواژه‌ها

Excess molar volume؛ n-butylacetate؛ 1-butanol؛ 1,2-butanediol؛ Molecular interactions

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