Oxidative coupling of thiols to disulfides in solution radiation with Trimethylammonium Fluorochromate(VI), [(CH3)3NH[CrO3F], on Silica Gel

Journal of the Iranian Chemical Research

مقاله 6، دوره 5، شماره 3، آذر 2012، صفحه 173-176   

نویسنده

Shahriar Ghammamy^*

Department of Chemistry, Faculty of Science, Imam Khomeini International University, Qazvin, Iran

چکیده

A mild and efficient method for the oxidative coupling of thiols by trimethylammonium fluorochromate
(TriMFC) in solution is reported. Trimethylammonium fluorochromate is efficient and new reagent, which
prepares easily and oxidizes thiols to the corresponding disulfides quickly. The reactions perform cleanly and
controlled to stop at the disulfide stage without over-oxidation side products.

کلیدواژه‌ها

Trimethylammonium fluorochromate(VI)؛ Heterogeneous oxidants؛ Silica gel؛ Oxidation

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