arylaminotetrazoles : via [2+3] cycloaddition of nitriles and sodium azide via solid acid catalysis

Journal of Chemical Reactivity and Synthesis

مقاله 3، دوره 4، شماره 2، آذر 2014، صفحه 15-24

نوع مقاله: Research Article

نویسندگان

Abbas Teimouri^{* 1}؛ Alireza Najafi Chermahini²

¹Payame Noor University (PNU), Isfahan, Iran

²2Department of Chemistry, Yasouj University, Yasouj, Iran

چکیده

The [3+2] cycloaddition between various nitriles and sodium azide proceeds smoothly in the presence of zeolite and sulfated Zircona as effective catalyst and in the water and DMF/MeOH, to give the corresponding arylaminotetrazoles in good to high yields. The reaction most probably precedes through the in situ formation of a catalyst azide species, followed by a successive [3+2] cycloaddition with the nitriles. This method has the advantages of high yields, simple methodology,and easy work-up. The catalyst can be recovered by simple filtration and reused in good yields

کلیدواژه‌ها

zeolite؛ Sulfated Zirconia؛ Green synthesis؛ arylaminotetrazoles

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