Efficient synthesis of arylaminotetrazoles as via [2+3] cycloaddition of nitriles and sodium azide via solid acid catalysis

Journal of Chemical Reactivity and Synthesis

مقاله 1، دوره 5، شماره 2، اسفند 2015، صفحه 1-10   

نوع مقاله: Research Article

نویسندگان

Abbas Teimouri^{* 1}؛ Alireza Najafi Chermahini²

¹Payame Noor University (PNU), Isfahan, Iran

²Department of Chemistry, Isfahan University of Technology, Isfahan, Iran

چکیده

The [3+2] cycloaddition between various nitriles and sodium azide proceeds smoothly in the presence of zeolite and sulfated Zircona as effective catalyst and in the water and DMF/MeOH, to give the corresponding arylaminotetrazoles in good to high yields. The reaction most probably precedes through the in situ formation of a catalyst azide species, followed by a successive [3+2] cycloaddition with the nitriles. This method has the advantages of high yields, simple methodology,and easy work-up. The catalyst can be recovered by simple filtration and reused in good yields.

کلیدواژه‌ها

zeolite؛ Sulfated Zirconia؛ Green synthesis؛ arylaminotetrazoles

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