Synthesis and Study on Conductivity of Urethane Acrylate/Polyaniline/CuO Nanocomposites

Journal of Applied Chemical Research

مقاله 6، دوره 12، شماره 4، دی 2018، صفحه 66-77   

نوع مقاله: Research Paper

نویسندگان

Zeinab Hesari¹؛ Behzad Shirkavand Hadavand^{* 2}

¹Young Researchers and Elites club, Science and Research Branch, Islamic Azad University, Tehran, Iran

²Department of Resin and Additives, Institute for Color Science and Technology, Tehran, Iran

چکیده

In this research, novel conductive nanocomposites containing urethane acrylate (UA) and
polyaniline/copper (II) oxide nanocomposites (PANi-CuO) were synthesized. At first
polyaniline/CuO nanocomposites with different amount of CuOnanoparticleswere prepared by
chemical oxidationpolymerization of aniline using ammonium peroxydisulfate as an oxidizing
agent. Afterward, UA-PANi-CuO nanocomposites were mixed and then cured by ultraviolet
irradiation. Analytical tests (FTIR and UV–vis spectroscopy, X-ray diffraction) approved chemical
structure of synthesized materials. The SEM images of the nanocomposites showed uniform
distribution of CuO nanoparticles in PANi matrix and UA-PANi-CuO in urethane acrylate matrix.
Electrical conductivity measurements of PANi-CuO nanocomposites revealed that the conductivity
of PANi decreased with adding content of CuO nanoparticles, also the conductivity of UA
increased with adding PANi-CuO.

کلیدواژه‌ها

Polyaniline؛ CuO nanoparticles؛ UV cure؛ Urethane acrylate؛ Electrical Conductivity