Consideration of C-H…O interaction in the heterocyclic organic-inorganic hybrid material: tri-prolinium12- phosphomolibdate heteropolyoxometalate

Journal of Chemical Reactivity and Synthesis

مقاله 5، دوره 8، شماره 3، آذر 2018، صفحه 26-32   

نوع مقاله: Research Article

نویسندگان

Masoud Mirzaei^{* 1}؛ Ali R. Salimia¹؛ Mohammad H. Alizadeh¹؛ Hossein Eshtiagh-Hosseini²؛ Hossein Razavi³

¹Department of Chemistry, Ferdowsi University of Mashhad, Mashhad P.O. Box 917791436, Iran

²Department of Chemistry, Ferdowsi University of Mashhad, Mashhad P.O. Box 917791436

³Department of Chemistry, Georgetown University, Washington, DC 20057, USA

چکیده

Crystallographic data analyses indicate that  three types of prolinium cations, along with two types of hydrogen  bonding,  produce and stabilize the helical structure of  triprolinium 12-phosphomolybdate. There are similarities between this organic-inorganic compound and peptides/proteins. The stronger “conventional” hydrogen bonds and the less common C-H…O attractions play critical roles in generating and stabilizing the DNA-like network