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Theoretical study of the effect of internal strain on the bond length and rate of hydrolysis in cyclic amides | ||
| Journal of Chemical Reactivity and Synthesis | ||
| مقاله 5، دوره 8، شماره 4، بهمن 2018، صفحه 33-37 اصل مقاله (250.84 K) | ||
| نوع مقاله: Research Article | ||
| نویسندگان | ||
| Mahdieh Entezari؛ Shahab Zomorod bakhsh | ||
| Department of Chemistry, Islamic azad university, mahshahr branch, Mahshahr, Iran | ||
| چکیده | ||
| The internal strain in cyclic amides are explained as a factor of resonance that are effected on the bond length C-N and are a major factor of rates of hydrolysis. The cyclic amides in this study are optimized by Gaussian program and the bond length of C-N in the rings are studied by HF/6-31G*. | ||
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آمار تعداد مشاهده مقاله: 147 تعداد دریافت فایل اصل مقاله: 250 |
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