Theoretical study of the effect of internal strain on the bond length and rate of hydrolysis in cyclic amides

Journal of Chemical Reactivity and Synthesis

مقاله 5، دوره 8، شماره 4، بهمن 2018، صفحه 33-37   

نوع مقاله: Research Article

نویسندگان

Mahdieh Entezari؛ Shahab Zomorod bakhsh

Department of Chemistry, Islamic azad university, mahshahr branch, Mahshahr, Iran

چکیده

The internal strain in cyclic amides are explained as a factor of resonance that are effected on the bond length C-N  and are a major factor of rates of hydrolysis. The cyclic amides in this study are optimized by Gaussian program and the bond length of C-N in the rings are studied by HF/6-31G*.