B-podands as efficient catalysts for the ring opening of epoxides in water: A versatile and atom economical method for the synthesis of vicinal azidoalcohols

Iranian Journal of Catalysis

مقاله 1، دوره 2، شماره 1، فروردین 2012، صفحه 1-5   

نویسندگان

Ali R. Kiasat^{* 1}؛ Fakhri Ataeian¹؛ Mehdi Fallah-Mehrjardi²

¹Department of Chemistry, College of Science, Shahid Chamran University, Ahvaz 61357-4-3169, I.R. Iran.

²Department of Marine Chemistry, Khorramshahr University of Marine Science and Technology, Khorramshahr 669, I.R. Iran.

چکیده

For the first time B-podands have been studied as an efficient and powerful catalysts in the ring opening of epoxides with azide anion in water. The reaction afforded the corresponding 1,2-azidoalcohols with high regioselectivity under mild reaction conditions and in a highly atom economic fashion.

کلیدواژه‌ها

Phase transfer catalyst؛ B-podands؛ 1؛ 2-Azidoalcohol؛ Epoxide؛ Atom economic؛ Ring Opening

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