1,3-Dichloro-5,5-dimethylhydantoin: an efficient catalyst for the solvent free synthesis of 1,8-dioxo-octahydro-xanthenes

Iranian Journal of Catalysis

مقاله 2، دوره 2، شماره 2، شهریور 2012، صفحه 57-61   

نویسندگان

Farhad Shirini^* ؛ Kurosh Rad-Moghadam؛ Tahereh Naghdi

Department of Chemistry, College of Science, University of Guilan, Rasht, zip code 41335, I.R. Iran

چکیده

This paper describes the applicability of 1,3-dichloro-5,5-dimethylhydantoin, as a cheap, stable and commercially available catalyst, in the promotion of the synthesis of 1,8-dioxo-octahydro-xanthenes (DOXOs) via the one-pot condensation of aldehydes and cyclic 1,3-dicarbonyl compounds. This novel synthetic method has the advantages of high yields, short reaction times, low cost and availability of the catalyst, solvent-free reaction conditions, simplicity and easy work-up compared to the conventional methods reported in the literature.

کلیدواژه‌ها

Aldehydes؛ 1؛ 8-Dioxo-octahydro-xanthenes؛ 3-Dichloro-5؛ 5-dimethylhydantoin؛ Cyclic 1؛ 3-dicarbonyl compounds؛ Solvent-free conditions

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