Brønsted acidic ionic liquid as a metal free catalyst for the one-pot synthesis of α-aminonitriles under mild and solvent-free conditions

Iranian Journal of Catalysis

مقاله 3، دوره 2، شماره 2، شهریور 2012، صفحه 63-68   

نویسندگان

Leila Khazdooz^{* 1}؛ Amin Zarei²؛ Abdol R. Hajipour³؛ Nafisehsadat Sheikhan⁴

¹Department of Science, Khorasgan Branch, Islamic Azad University, Isfahan 81595-158, Iran.

²Department of Science, Fasa Branch, Islamic Azad University, Post Box No 364, Fasa, 7461713591, Fars, Iran.

³Dept. of Pharmacology, University of Wisconsin, Medical School, Madison, 53706-1532, WI, USA. Pharmaceutical Research Laboratory, College of Chemistry, Isfahan University of Technology, Isfahan 84156, IR Iran.

⁴Department of Science, Najafabad Branch, Islamic Azad University, Isfahan, Iran.

چکیده

An efficient, mild and environmentally friendly method was developed for the Strecker reaction to synthesize α-aminonitriles in the presence of methyl imidazolium hydrogen sulfate ([Hmim][HSO₄]) as an efficient catalyst. These syntheses were performed via a one-pot three-component condensation of aldehydes (or ketones), amines, and trimethylsilyl cyanide under mild and solvent free conditions.

کلیدواژه‌ها

Strecker؛ α-Amino nitriles؛ Methyl imidazolium hydrogen sulfate؛ Solvent free conditions

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