Synthesis of 4,4′-(arylmethylene)bis(1H-pyrazol-5-ols) via multi-component reactions by using silica-bonded sulfamic acid derivatives

Iranian Journal of Catalysis

مقاله 4، دوره 2، شماره 2، شهریور 2012، صفحه 69-74   

نویسندگان

Shekoofeh Tayebi¹؛ Khodabakhsh Niknam^{* 2}

¹Young Researchers Club, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran.

²Department of Chemistry, Faculty of Sciences, Persian Gulf University, Bushehr 75169 Iran.

چکیده

The one-pot, multi-component synthesis of 4,4′-(arylmethylene)bis(1H-pyrazol-5-ols) by tandem Knoevenagel-Michael reaction of phenylhydrazine, ethyl acetoacetate and aldehydes in the presence of silica-bonded N-propylpiperazine sulfamic acid (SBPPSA) as a recyclable solid acid catalyst was reported. SBPPSA showed much the same efficiency when used in consecutive reaction runs.

کلیدواژه‌ها

Silica-bonded N-propylpiperazine sulfamic acid؛ Catalyst؛ Aldehydes؛ 4؛ 4′-(Arylmethylene)bis(1H-pyrazol-5-ols)؛ Multi-component reactions

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