Nano SiO2/H2SO4 as catalyst for the Beckmann rearrangement and deoximation of aldoximes

Iranian Journal of Catalysis

مقاله 5، دوره 3، شماره 1، خرداد 2013، صفحه 27-32   

نویسندگان

Marziyeh Bagheri؛ Mostafa Karimkoshteh^*

Department of Chemistry, Faculty of Science, Urmia University, Urmia 57159-165, Iran.

چکیده

Nano silica-H2SO4 is an efficient and mild catalysis system for the regeneration of aldehyde from aldoximes. Ketoximes are converted to amides by Beckmann rearrangement in the presence of nano silica-H2SO4. The reactions are carried out in solvent-free conditions under microwave irradiation (600 W) within 50-120 sec in good yields.

کلیدواژه‌ها

oxime؛ Nano SiO2؛ Amide؛ Carbonyl compound

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