Application of multipurpose dimethyl formamide-like task specific ionic liquid as a recyclable reagent for direct iodination of alcohols

Iranian Journal of Catalysis

مقاله 5، دوره 1، شماره 2، اسفند 2011، صفحه 79-86   

نویسندگان

Ahmed Ali Hullio^* ؛ G.M. Mastoi

Dr. M.A Kazi Institute of Chemistry, University of Sindh Jamshoro-76080 Sindh, Pakistan.

چکیده

A direct and an efficient conversion of a wide range of primary, secondary even tertiary alcohols to the corresponding iodides have been achieved under ionic liquid conditions. The method involves preparation of ionic liquid-based iminium chloride intermediate from DMF-like ionic liquid then stirring it with alcohol in present of sodium iodide. The higher yields of alkyl iodides were obtained within minimum time with simplest operational procedure. The DMF-like ionic liquids could be recycled.

کلیدواژه‌ها

DMF-like ionic liquid؛ Iminium chloride؛ Vilsmier reagent؛ Thioiminium salt؛ Alcohols and alkyl iodides

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