Thermodynamic study of an effective catalytic system, hydrogen peroxide and methyltrioxorhenium

Iranian Journal of Catalysis

مقاله 3، دوره 4، شماره 3، آذر 2014، صفحه 143-148   

نوع مقاله: Articles

نویسنده

Fatemeh Niroomand Hosseini^*

Department of Chemistry, Shiraz Branch, Islamic Azad University, Shiraz, Iran.

چکیده

The thermodynamic of the known and very effective catalytic system, hydrogen peroxide (H2O2) and methyltrioxorhenium (MTO) is studied in different solvents using UV-Visible spectroscopic method. The thermodynamic parameters (ΔG, ΔH and ΔS) for two equilibrium reactions, MTO + H2O2 ⇌ A + H2O and A + H2O2 ⇌ B.H2O (A, [MeRe(O)2(O2)]; B.H2O, [MeRe(OH2)(O)(O2)2]), are determined. The obtained free energies of the reactions depend on dielectric constants of solvent, which are explained by Onsager’s reaction field theory.

کلیدواژه‌ها

Methyltrioxorhenium؛ Hydrogen peroxide؛ Thermodynamic study

مراجع

[1] W.A. Herrmann, R.W. Fischer, D.W. Marz, Angew. Chem. Int. Ed. 30 (1991) 1638-1641.
[2] R. Saladino, V. Neri, P. Checconi, I. Celestino, L. Nencioni, A.T. Palamara, M. Crucianelli, Chem. Eur. J. 19 (2013) 2392-2404.
[3] S. Yamazaki, J. Org. Chem. 77 (2012) 9884-9888.
[4] T. Hwang, B.R. Goldsmith, B. Peters, S.L. Scott, Inorg. Chem. 52 (2013) 13904-13917.
[5] W.A. Herrmann, R.M. Kratzer, H. Ding, W.R. Thiel, H. Glas, J. Organomet. Chem. 555 (1998) 293-295.
[6] C.C. Romao, F.E. Kuhn, W.A. Herrmann, Chem. Rev. 97 (1997) 3197-3246.
[7] N. Al-Rawashdeh, A. Al-Ajlouni, S. Bukallah, N. Bataineh, J. Incl. Phenom. Macrocycl. Chem. 70 (2011) 471-480.
[8] S. Yamazaki, Org. Biomol. Chem. 8 (2010) 2377-2385.
[9] R. Yang, Y. Zhang, J. Zhao, Catal. Commun. 12 (2011) 923-926.
[10] F.E. Kuhn, A.M. Santos, W.A. Herrmann, Dalton Trans. (2005) 2483-2491.
[11] H. Tan, J.H. Espenson, Inorg. Chem. 37 (1998) 467-472.
[12] G.B. Shul'pin, M.V. Kirillova, Y.N. Kozlov, L.S. Shulpina, A.R. Kudinov, A.J. Pombeiro, J. Catal. 277 (2011) 164-172.
[13] F.P. Ballistreri, G.A. Tomaselli, R.M. Toscano, Tetrahedron Lett. 50 (2009) 6231-6232.
[14] G.S. Owens, J. Arias, M.M. Abu-Omar, Catal. Today 55 (2000) 317-363.
[15] J.H. Espenson, Chem. Commun. (1999) 479-488.
[16] M.M. Abu-Omar, P.J. Hansen, J.H. Espenson, J. Am. Chem. Soc. 118 (1996) 4966-4974.
[17] W.A. Herrmann, R.W. Fischer, W. Scherer, M.U. Rauch, Angew. Chem. Int. Ed. 32 (1993) 1157-1160.
[18] C. Coperet, H. Adolfsson, K.B. Sharpless, Chem. Commun. (1997) 1565-1566.
[19] M.L. Kuznetsov, A.J. Pombeiro, Inorg. Chem. 48 (2009) 307-318.
[20] F.N. Hosseini, S.M. Nabavizadeh, G. Azimi, J. Sol. Chem. 42 (2013) 2137-2148.
[21] C. Di Valentin, R. Gandolfi, P. Gisdakis, N. Rosch, J. Am. Chem. Soc. 123 (2001) 2365-2376.
[22] S.M. Nabavizadeh, M. Rashidi, J. Am. Chem. Soc. 128 (2006) 351-357.
[23] F.N. Hosseini, K. Kamali, S.M. Nabavizadeh, Polyhedron 30 (2011) 814-820.
[24] W.A. Herrmann, R.M. Kratzer, R.W. Fischer, Angew. Chem. Int. Ed. 36 (1997) 2652-2654.
[25] S. Yamazaki, J.H. Espenson, P. Huston, Inorg. Chem. 32 (1993) 4683-4687.
[26] Y. Marcus, Chem. Soc. Rev. 22 (1993) 409-416.
[27] A. Taha, A.M. Kiwan, New J. Chem. 25 (2001) 502-508.
[28] W.R. Fawcett, J. Phys. Chem. 97 (1993) 9540-9546.
[29] M.J. Kamlet, J.L.M. Abboud, M.H. Abraham, R. Taft, J. Org. Chem. 48 (1983) 2877-2887.
[30] J.L. Abboud, R. Notari, Pure Appl. Chem. 71 (1999) 645-718.
[31] J.N. Wilson, Chem. Rev. 25 (1939) 377-406.
[32] L. Onsager, J. Am. Chem. Soc. 58 (1936) 1486-1493.