Melamine trisulfonic acid: An efficient and recyclable solid acid catalyst for the green synthesis of Biscoumarin derivatives

Iranian Journal of Catalysis

مقاله 9، دوره 5، شماره 1، خرداد 2015، صفحه 65-71   

نوع مقاله: Articles

نویسندگان

Nasir Iravani^{* 1}؛ Mosadegh Keshavarz²؛ Maryam Mousavi³؛ Mojtaba Baghernejad⁴

¹Department of Chemistry, Faculty of Science, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran.

²Department of Gas and Petroleum, Yasouj University, Yasouj, Zip Code 75918-74831, Iran

³Department of Chemistry, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran

⁴Young and Reasearcers Elite, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran

چکیده

A novel catalytic synthesis of 3,3'-(arylmethylene)-bis-(4-hydroxy-2H-chromene-2-one) derivatives from a tandem condensation reaction of 4-hydroxycoumarin and aromatic aldehydes has been developed. The reaction occurs in water in the presence of Melamine trisulfonic acid as catalyst to give the corresponding products in good to high yields. This green approach has several advantages such as short reaction times, clean reaction profiles, and simple experimental and workup procedures. Moreover, the catalyst can be easily recovered by filtration and used at least seven times with only slight reduction in its catalytic activity. The results of the presented protocol in comparison with the different available catalysts in condensation reaction of benzaldehyde with 4-Hydroxycoumarin show that MTSA presented better results due to the structure of MTSA.

کلیدواژه‌ها

Aromatic aldehydes؛ Biscoumarins؛ 4-hydroxycoumarin؛ Melamine trisulfonic acid

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