Nanomagnetite-Fe3O4 as a highly efficient, green and recyclable catalyst for the synthesis of 4,4´-(arylmethylene)-bis(3-methyl-1-phenyl-1H-pyrazol-5-ol)s

Iranian Journal of Catalysis

مقاله 3، دوره 5، شماره 4، اسفند 2015، صفحه 311-320   

نوع مقاله: Articles

نویسندگان

Abdolkarim Zare^{* 1}؛ Fereshteh Abi²؛ Vahid Khakyzadeh³؛ Ahmad Reza Moosavi-Zare⁴؛ Alireza Hasaninejad⁵؛ Mahmoud Zarei³

¹Department of Chemistry, Payame Noor University, PO BOX 19395-4697, Tehran, Iran.

²Department of Chemistry, Payame Noor University, PO BOX 19395-4697, Tehran, Iran

³Faculty of Chemistry, Bu-Ali Sina University, Hamedan, 6517838683, Iran

⁴Department of Chemistry, University of Sayyed Jamaleddin Asadabadi, Asadabad 6541835583, Iran

⁵Department of Chemistry, Faculty of Sciences, Persian Gulf University, Bushehr 75169, Iran

چکیده

Nanomagnetite-Fe3O4 is used as a highly efficient, mild, green and recyclable nanomagnetite catalyst for the synthesis of 4,4´-(arylmethylene)-bis(3-methyl-1-phenyl-1H-pyrazol-5-ol) derivatives in solvent-free conditions. The condensation reaction of 3-methyl-1-phenyl-1H-pyrazol-5(4H)-one with aromatic aldehydes affords the title compounds in high yields and short reaction times. The nanocatalyst is reusable for seven times without significant loss of its catalytic activity. Short reaction times, high yields, generality, efficiency, recyclability of the catalyst for seven times, simple purification, clean reaction, and agreement with the green chemistry protocols are some advantages of in this method. the catalyst was characterized by transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometer (XRD) and vibrating sample magnetometer (VSM).

کلیدواژه‌ها

Nanomagnetite-Fe3O4؛ Nanomagnetite؛ 4؛ 4´-(Arylmethylene)-bis(3-methyl-1-phenyl-1H-pyrazol-5-ol)؛ 3-Methyl-1-phenyl-1H-pyrazol-5(4H)-one؛ Aromatic aldehyde

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