Application of silica vanadic acid as a dual Lewis and Bronsted acid catalytic ability in Dakin West reaction

Iranian Journal of Catalysis

مقاله 12، دوره 6، شماره 2، شهریور 2016، صفحه 173-179   

نوع مقاله: Articles

نویسندگان

Malihe Safaiee^{* 1}؛ Mohammad Ali Zolfigol^{* 2}؛ Fatemeh Derakhshan-Panah²؛ Mohammad Mokhlesi³

¹Department of Medicinal Plants Production, Nahavand University, Nahavand, 6593139565, Iran.

²Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan 6517838683, Iran.

³Pishro Parsian Company, 11th floor, No. 1917, Amir Bldg, above the four way the Jalal Alahmad, North Kargar Ave, PC: 1439713134, Tehran, Iran.

چکیده

Silica Vanadic Acid, SVA, (oxo-vanadium has been supported on silica) as a dual Lewis and Bronsted acid ability was prepared and efficiently catalyzed one-pot multi-component condensation of enolizable ketones or alkyl acetoacetates with aromatic aldehydes, acetonitrile and acetyl chloride. The described reaction was produced β-acetamido ketone or ester derivatives in high to excellent yields in relatively short reaction times in heterogeneous catalytic system at room temperature. Other advantages of this method is applicable at large scales without significant loss of the yields. In addition, this method is superior to reported methods, for the synthesis of β-acetamido ketone or ester derivatives.

کلیدواژه‌ها

β-Acetamido ketone؛ β-Acetamido ester؛ Silica vanadic acid (SVA)؛ Enolizable ketone؛ Multi-component reactions؛ Dakin west

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