Preparation and application of HMCM-22 zeolite as an efficient solid acid catalyst for the synthesis of acetals

Iranian Journal of Catalysis

مقاله 5، دوره 7، شماره 2، شهریور 2017، صفحه 131-136   

نوع مقاله: Articles

نویسندگان

Hosein Hoseini¹؛ Maryam Gorjizadeh²؛ Soheil Sayyahi^{* 1}؛ Amirhossein Shahbazi Kootenaei³

¹Department of Chemistry, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran.

²Department of Chemistry, Shoushtar Branch, Islamic Azad University, Shoushtar, Iran.

³Department of Chemical Engineering, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran.

چکیده

HMCM-22 with a Si:Al molar ratio of 15:1 has been shown to effectively catalyze the synthesis of acetals with 100% selectivity by the reaction of aldehydes with methanol under reflux conditions. Platelet HMCM-22 particles were prepared by the static strategy and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), BET techniques and N₂-adsorption/desorption analysis. The catalyst was recovered by simple filtration and reused for several cycles without considerable loss of activity.

HMCM-22 with a Si:Al molar ratio of 15:1 has been shown to effectively catalyze the synthesis of acetals by the reaction of aldehydes with methanol under reflux conditions. Platelet HMCM-22 particles were prepared by static method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), BET techniques and N2-adsorption/desorption analysis. The catalyst was recovered by simple filtration and reused for several cycles without considerable loss of activity.

کلیدواژه‌ها

HMCM-22؛ Heterogeneous catalyst؛ Acetals؛ Protection

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