Preparation and characterization of ionic liquid functionalized SBA-15 and its application in the synthesis of 2,3-dihydroquinazolinones

Iranian Journal of Catalysis

مقاله 6، دوره 7، شماره 2، شهریور 2017، صفحه 137-145   

نوع مقاله: Articles

نویسندگان

Ghodsi Mohammadi Ziarani^{* 1}؛ Leila Seiedakbari¹؛ Parisa Gholamzadeh¹؛ Alireza Badiei²

¹Department of Chemistry, Alzahra University, Vanak Square, Tehran, Iran, P.O. Box 1993893973.

²School of Chemistry, College of Science, University of Tehran, Tehran, Iran.

چکیده

N-Methyl-Nʹ-propyltrimethoxysillylimidazolium chloride was prepared as ionic liquid (IL) containing silylating agent and then used for modification of the internal surface of SBA-15 to gain a heterogeneous ionic liquid catalyst. Subsequently, the obtained SBA-IL was characterized using various techniques, including SEM and TEM images, FT-IR, X-ray diffraction, TGA/DTA and BET analyses. It was found that the uniform SBA-15 particles, with a dimension of 400-800 nm, showed the decreasing in the pore volume, surface area, and pore diameter after modification process which is as a results of incorporating imidazole groups onto the pores of SBA-15. Afterward, catalytic activity of SBA-IL was investigated in the synthesis of 2,3-dihydroquinazolinones under solvent free condition.

کلیدواژه‌ها

Quinazoline؛ SBA-15 functionalized ionic liquid؛ Nano-catalyst؛ Isatoic anhydride؛ One-pot reaction

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