Effects of metal oxide catalysts on the photodegradation of antibiotics effluent

Iranian Journal of Catalysis

مقاله 1، دوره 8، شماره 4، اسفند 2018، صفحه 241-247   

نوع مقاله: Articles

نویسندگان

Chaimaa EL Bekkali¹؛ Habiba Bouyarmane¹؛ Said Laasri²؛ Abdelaziz Laghzizil^{* 1}؛ Ahmed Saoiabi¹

¹Laboratoire de Chimie Appliquée des Matériaux, Université Mohamed V, Faculté des Sciences, BP.1014, Rabat, Morocco.

²Laboratoire des Sciences de l'Ingénieur Pour l'Énergie, École Nationale des Sciences Appliquées-El Jadida-Morocco.

چکیده

The current study examined the effect of metal oxide catalysts on the sorption and photocatalytic efficiencies for the removal of ciprofloxacin and ofloxacin in water. ZnO and TiO₂ catalysts are prepared using a suitable method based on the sol-gel process, which have a great change in structural and textural properties. The structure and surface area of the synthesized catalysts were characterized, and used as sorbents/catalysts to remove antibiotics from water. Results showed a high adsorption capacity for the Titania oxide related to its great surface area, it is about 280 m² g^-1, compared to that of ZnO catalyst with only 19 m² g^-1. However, both photocatalysts exhibit a difference in photocatalytic activity versus both drugs. Therefore, ZnO, as a competitor catalyst for the TiO₂, provides the most effective treatment of contaminated water with antibiotic pollutants to produce suitable reused water.

کلیدواژه‌ها

ZnO؛ TiO2؛ Catalysts؛ Antibiotics؛ Photocatalytic activity, Removal

مراجع

[1] V. Homen, L. Santos, J. Environ. Manage. 92 (2011) 2304-47.
[2] M. Amini, M. Khanavi, A. Shafiee, Iran. J. Pharm. Res. 2 (2004) 99-101.
[3] E. Zuccato, S. Castiglioni, R. Fanelli, G. Reitano, D. Calamari, New York, Springer-Verlag, 2004.
[4] N. Ajoudanian, A. Nezamzadeh-Ejhieh, Mater. Sci. Semicond. Proces. 36 (2015) 162-169.
[5] A. Pourtaheri, A. Nezamzadeh-Ejhieh, Chem. Eng. Res. Design. 104 (2015) 835-843.
[6] L. Elsellami, N. Hafidhi, F. Dappozze, A. Houas, C. Guillard, Chin. J. Catal. 36 (2015) 1818-1824.
[7] A.M. Ferrari-Lima, R.P.D. Souza, S.S. Mende, R.G. Marques, M.L.Gimenes, N.R.C. Fernandes-Machado, Catal. Today 241 (2015) 40-46.
[8] G.S. Pozan, A. Kambur, Chemosphere 105 (2014) 152-159.
[9] A. Nezamzadeh-Ejhieh, M. Bahrami, Des. Water Treat. 52 (2014) 3328-3337.
[10] A. Nezamzadeh-Ejhieh, Z. Ghanbari-Mobarakeh, J. Ind. Eng. Chem. 21 (2015) 668-676.
[11] D. Li, H. Haneda, Chemosphere 51 (2003) 129-137.
[12] V. Srikant, V.D.R. Clarkea, J. Appl. Phys. 83 (1998) 5447-5451.
[13] E. Elmolla, M. Chaudhuri, J. Hazard. Mater. 173 (2011) 445-449.
[14] A. Nezamzadeh-Ejhieh, M. Bahrami, Des. Water Treat. 55 (2015) 1096-1104.
[15] G.H. Safari, M. Hoseini, M. Seyedsalehi, H. Kamani, J. Jaafari, A.H. Mahvi, Int. J. Environ. Sci. Technol. 12 (2015) 603-616.
[16] R.A. Palominos, M.A. Mondaca, A. Giraldo, G. Penuela, M. Perez-Moya, H.D. Mansilla, Catal. Today 144 (2006) 100-112.
[17] H. F. Moafi, Iran. J. Catal. 6 (2016) 281-292.
[18] B. Khodadadi, Iran. J. Catal. 6 (2016) 305-311.
[19] A. Besharati-Seidani, Iran. J. Catal. 6 (2016) 447-454.
[20] S. Dianat, Iran. J. Catal. 8 (2018) 121-132.
[21] S. Feizpoor, A. Habibbi-Yangjeh, Mater. Res. Bull. 99 (2018) 93-102.
[22] M.M. Khan, S.A. Ansari, D. Pradhan, M.O. Ansari, D.H. Han, J. Lee, J. Mater. Chem. A 2 (2014) 637-644.
[23] R. Nosrati, A. Olad, R. Maramifar, Environ. Sci. Pollut. 19 (2012) 2291-2299.
[24] H.R. Pouretedal, M. Ahmadi, Iran. J. Catal. 3 (2013) 149-155.
[25] L. Vafayi, S. Gharibe, Iran. J. Catal. 5 (2015) 365-371.
[26] M. Giahi, A. H. Dargahi, Iran. J. Catal. 6 (2016) 381-387.
[27] M. Bordbar, S. Forghani-Pilerood, A. Yeganeh-Faal, Iran. J. Catal. 6 (2016) 415-421.
[28] S. Aghdasi, M. Shokri, Iran. J. Catal. 6 (2016) 481-487.
[29] M. Pirhashemi, A. Habibi-Yangjeh, Sep. Purif. Technol. 193 (2018) 69-80.
[30] H. Bouyarmane, S. Saoiabi, I. El Hanbali, M. El Karbane, A. Rami, S. Masse, A. Laghzizil, T. Coradin, Eur. Phys. J. Spec. Top. 224 (2015) 1861-1869.
[31] M. Anari-Anaraki, A. Nezamzadeh-Ejhieh, J. Colloid Interf. Sci. 440 (2015) 272-281.
[32] S.A. Hosseini, R. Saeedi, Iran. J. Catal. 7 (2017) 37-46.
[33] S.D. Khairnar, M.R. Patil, V.S. Shrivastava, Iran. J. Catal. 8 (2018) 143-150.
[34] A.Nezamzadeh-Ejhieh, S. Hushmandrad, Appl. Catal. A 388 (2010) 149-159.
[35] D. Li, W. Shi, Chin. J. Catal. 37 (2016) 792-799.
[36] I. Michael, E. Hapeshi, C. Michael, D. Fatta-Kassinos, Water Res. 44 (2010) 5450-5462.
[37] A. Kaur, G. Gupta, A.O. Ibhadon, D.B. Salunke, A.S.K. Sinha, S.K. Kansal, J. Environ. Chem. Eng. 6 (2018) 3621-3630.
[38] M. El-Kemary, H. El-Shamy, I. El-Mehasseb, J. Lumin. 130 (210) 2327-2331.
[39] V. Augugliaro, M. Litter, L. Palmisano, J. Soria, J. Photochem. Photobiol. C 7 (2006) 127-144.
[40] S. Ahmed, M.G. Rasul, R. Brown, M.A. Hashib, J. Environ. Manage. 92 (2011) 311-330.