Using a bithiazole complex as precursor to synthesis of CdO-CdS nanocomposite via direct thermal decomposition

International Journal of Nano Dimension

مقاله 8، دوره 1، شماره 1، مهر 2010، صفحه 65-76   

نوع مقاله: Reasearch Paper

شناسه دیجیتال (DOI): 10.7508/ijnd.2010.0x.007

نویسندگان

A. Hosseinian^{* 1}؛ A.R. Mahjoub²؛ M. Movahedi³

¹Department of Engineering Science, Faculty of Engineering, University of Tehran,Tehran, Iran.

²Department of chemistry, Tarbiat Modares University,Tehran ,Iran

³Department of Chemistry, Payame Noor University, Isfahan, Iran.

چکیده

A new tris-chelate Cd(II) complex, [Cd(DADMBTZ)3](ClO3)2 has been successfully synthesized and characterized by IR, 1H, 13C NMR spectroscopy, elemental analysis and single crystal X-ray determination. The thermal behavior, UV-Vis and fluorescence spectra of compound were studied. In reaction with DADMBTZ, Cadmium (II) forms a tris-chelate complex with nearly C3 symmetry for coordination polyhedron, DADMBTZ acts as a bidentate ligand. In complex the ClO3 - anions are symmetrically different. Complex makes 2-D and 3-D networks via N-H…O and N-H…N hydrogen bonds, respectively. The nanocomposite CdO-CdS have been prepared using [Cd(DADMBTZ)3](ClO3)2 as precursor via thermal decomposition. As-prepared CdO-CdS nanocomposite was characterized By X-ray diffraction measurements (XRD), scanning electron microscopy (SEM).

کلیدواژه‌ها

Bithiazole؛ complex؛ CdO-CdS؛ Nanocomposite؛ Thermal decomposition