Nano-SiO2/hexamethylenetetramine promoted synthesis of pyrano[2,3-c] pyrazoles under solvent-free conditions

Iranian Journal of Catalysis

مقاله 2، دوره 10، شماره 1، خرداد 2020، صفحه 17-22   

نوع مقاله: Articles

نویسندگان

Bi Bi Fatemeh Mirjalili^* ؛ Mina Keihanfar

Department of Chemistry, Faculty of Sciences, Yazd University, P.O. Box 89195-741, Yazd, I.R. Iran.

چکیده

In this study, the nano-SiO₂/hexamethylenetetramine as a new basic heterogeneous nanocatalyst was prepared and used for the synthesis of pyranopyrazole via the four-component reaction. Various aldehydes, hydrazine hydrate, ethyl acetoacetate and malononitrile were reacted at room temperature under solvent-free and grinding conditions. The morphology and structure of nano-catalyst were investigated by techniques such as FT-IR spectroscopy, FESEM, TEM, XRD, CHNS elemental analyzer and TGA. The structure of pyranopyrazoles was determined by spectroscopic data of FTIR and NMR. The principal affairs of this procedure are easy work-up, high yields, mild conditions and short reaction times.

کلیدواژه‌ها

Nano-SiO2/hexamethylenetetramine؛ Multicomponent reactions؛ Pyrano[2,3-c]pyrazole؛ Basic nanocatalyst؛ Reusable catalyst

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