Novel and cost-effective biocatalyst consisting of nanofibrillated cellulose and TiCl3 for the synthesis of 2,3'-dihydroquinazolin-4-(1H)-ones

Iranian Journal of Catalysis

مقاله 8، دوره 9، شماره 1، خرداد 2019، صفحه 71-77   

نوع مقاله: Articles

نویسندگان

Hannaneh Heidari^* ؛ Kobra Nikoofar^* ؛ Yeganeh Shahedi

Department of Chemistry, Faculty of Physics and Chemistry, Alzahra University. P.O. Box 1993893973, Tehran, Iran.

چکیده

A novel and cost-effective catalyst for synthesis of 2,3'-dihydroquinazolin-4-(1H)-ones was developed utilizing a combined nanocomposite obtained from bonding TiCl₃ to hydroxyl groups of nanofibrillated cellulose as a green and inexpensive support.The structure of the catalyst was investigated using the Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) techniques and transmission electron microscopy (TEM). The prepared new nanopolymer-based composite has been investigated successfully to obtain some 2,3'-dihydroquinazolin-4-(1H)-ones via the reaction of 2-aminobenzamide and various kinds of aldehydes/ cyclic ketones in refluxing ethanol. Short reaction times, the low amount of catalyst, high yields of products, utilizing a wide-range of aldehydes/ ketones, easy work-up procedure, in addition to the accelerating effect of the newly synthesized biodegradable nano composite, are some highlighted features of the reported protocol.

کلیدواژه‌ها

Nanofibrillated cellulose؛ Titanium chloride؛ Heterogeneous catalyst؛ 2,3'-Dihydroquinazolin-4-(1H)-ones

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