Functionalization of Carboxylate Multi Walled Carbon Nanotube with pyrano[2,3-d]pyrimidinone Derivatives by DABCO as a Catalyst in Green Media

Journal of Applied Chemical Research

مقاله 1، دوره 13، شماره 2، مرداد 2019، صفحه 8-17   

نوع مقاله: Research Paper

نویسندگان

Bahram Pourhasan^{* 1}؛ Abolghasem Shameli²

¹Department of Chemistry, Dezful Branch, Islamic Azad University, Dezful, Iran

²Department of Chemistry, Faculty of Science, Omidiyeh Branch, Islamic Azad University, Omidiyeh, Iran

چکیده

1, 4-Diazabicyclo [2.2.2] octane (DABCO) was employed as a catalyst for one-pot synthesis of pyrano[2,3-d] pyrimidinone derivatives and MWNT- pyrimidinones from condensation reactions of aromatic aldehydes, malononitrile and thiobarbituric acid and MWNT-COCl . This method delivers the advantages of a simple method, environment friendly procedure, mild reaction conditions and high returns. The materials were characterized by Fourier transform infrared spectroscopy, nuclear magnetic resonance, mass spectroscopy, elemental analysis, scanning electron microscopy and Thermogravimetric analysis.

کلیدواژه‌ها

MWNT؛ Pyrano[2؛ 3-d]pyrimidinone؛ Thiobarbuturbic acid؛ Malononitrile؛ aldehyde