Oxidation of greenhouse gases, CH4 and CO, over LaMnxNi1-xO3±δ mixed oxide

Iranian Journal of Catalysis

مقاله 9، دوره 9، شماره 4، اسفند 2019، صفحه 357-368   

نوع مقاله: Articles

نویسندگان

Farhad Banisharif^{* 1}؛ Mohammad Reza Dehghani¹؛ Golshan Mazloom²؛ Yahya Hojatpanah¹

¹Chemical Engineering Department, School of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology, Tehran, Iran.

²Department of Chemical Engineering, Faculty of Engineering, University of Mazandaran, Babolsar, Iran.

چکیده

The performance of LaMn_xNi_1-xO_3±δ perovskite mixed oxides (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9, 1) which were prepared by different methods, the Pechini and sol-gel methods in the oxidation of greenhouse gases, CH₄ and CO, has been investigated. All samples were characterized using Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy and N₂ adsorption. The results showed that Pechini samples are more active and stable than the sol-gel samples. The partially substituted Ni samples exhibited higher catalytic performance as compared to the LaMnO₃ due to the structural defects. But, the high substitution of Ni gradually deforms the structure to rhombohedra, decreases surface area and reduces the number of active Mn sites. Therefore, the catalytic performance passes through a maximum with respect to Ni content. LaMn_0.3Ni_0.7O_3±δ prepared by the Pechini method is more active than others in the oxidation of CH₄ and CO.

کلیدواژه‌ها

Perovskite mixed oxide؛ LaMnxNi1-xO3±δ؛ Greenhouse gas؛ Methane combustion؛ CO oxidation

مراجع

[1] Z. Li, G.B. Hoflund, J. Nat. Gas Chem. 12 (2003) 153-160.
[2] H. He, M. Liu, H. Dai, W. Qiu, X. Zi, Catal. Today 126 (2007) 290-295.
[3] S. Ordóñez, J.R. Paredes, F.V. Díez, Appl. Catal. A 341 (2008) 174-180.
[4] J.H.G. Rangel, P.R.G. Gonçalves Jr, M.M. Oliveira, M.I.B. Bernardi, Elson Longo, L.E.B. Soledade, I.M.G. Santos, A.G. Souza, Mater. Res. Bull. 43 (2008) 825-835.
[5] S. Cimino, A. Di Benedetto, R. Pirone, G. Russo, Catal. Today 83 (2003) 33-43.
[6] R. Spinicci, A. Delmastro, S. Ronchetti, A. Tofanari, Mater. Chem. Phys. 78 (2003) 393-399.
[7] S. Cimino, S. Colonna, S. De Rossi, M. Faticanti, L. Lisi, I. Pettiti, P. Porta, J. Catal. 205 (2002) 309-317.
[8] C. Gong, F. Guoliang, H. Yanfeng, S. Chonglin, H. Qifei, Z. Zhongrong, Front. Chem. Sci. Eng. 1 (2007) 6-10.
[9] G. Xu, H. Bai, X. Huang, W. He, L. Li, G. Shen, G. Han, J. Mater. Chem. A 3 (2015) 547-554.
[10] E. Campagnoli, A. Tavares, L. Fabbrini, I. Rossetti, Y.A. Dubitsky, A. Zaopo, L. Forni, Appl. Catal. B 55 (2005) 133-139.
[11] X. Yan, Q. Huang, B. Li, X. Xu, Y. Chen, S. Zhu, S. Shen, J. Ind. Eng. Chem. 19 (2013) 561-565.
[12] H. Ziaei-Azad, A. Khodadadi, P. Esmaeilnejad-Ahranjani, Y. Mortazavi, Appl. Catal. B 102 (2011) 62-70.
[13] Y. Ding, S. Wang, L. Zhang, Z. Chen, M. Wang, S. Wang, Catal. Commun. 97 (2017) 88-92.
[14] Z. Zhang, Z. Kong, H. Liu, Y. Chen, Front. Chem. Sci. Eng. 8 (2014) 87-94.
[15] J. Yang, Y. Guo, Chinese Chem. Lett. 29 (2018) 252-260.
[16] K.S. Song, H.X. Cui, S.D. Kim, S.K. Kang, Catal. Today 47 (1999) 155-160.
[17] C. Shi, H. Chang, C. Wang, T. Zhang, Y. Peng, M. Li, Y. Wang, J. Li, Ind. Eng. Chem. Res. 57 (2018) 920-926.
[18] Y. Shao, X.F. Wang, M. Ao, C.R. Gong, G.L. Fan, H.F. Chen, Front. Mater. Sci. 6 (2012) 304-310.
[19] W. Yue-Hui, L. Lai-Tao, L. Wei, Russ. J. Phys. Chem. A 84 (2010) 405-408.
[20] R.J.H. Voorhoeve, D.W. Johnson, J.P. Remeika, P.K. Gallagher, Science 195 (1977) 827-833.
[21] R. Ran, X. Wu, D Weng, J. Alloys Comp. 414 (2006) 169-174.
[22] H. Falcón, J.A. Barbero, J.A. Alonso, M.J. Martínez-Lope, J.L.G. Fierro, Chem. Mater. 14 (2002) 2325-2333.
[23] L.G. Tejuca, J.L.G. Fierro, J.M. Tascón, Adv. Catal. 36 (1989) 237-328.
[24] S. Royer, D. Duprez, ChemCatChem 3 (2011) 24-65.
[25] T. Seiyama, Catal. Rev. 34 (1992) 281-300.
[26] M. Parvary, S.H. Jazayeri, A. Taeb, C. Petit, A. Kiennemann, Catal. Commun. 2 (2001) 357-362.
[27] H. Arai, T. Yamada, K. Eguchi, T. Seiyama, Appl. Catal. 26 (1986) 265-276.
[28] A.C. Terracciano, S.T. De Oliveira, S.S. Vasu, N. Orlovskaya, Exp. Therm. Fluid Sci. 90 (2018) 330-335.
[29] D.A. Hassan, J. Xu, Y. Chen, L. Li, R. Zeng, Mater. Res. Bull. 79 (2016) 69-72.
[30] H. Wang, X. Dong, T. Zhao, H. Yu, M. Li, Appl. Catal. B 245 (2019) 302-313.
[31] R. Benakcha, M. Omari, Inorg. Nano-Met. Chem. 47 (2017) 1103-1109.
[32] G. Saracco, G. Scibilia, A. Iannibello, G. Baldi, Appl. Catal. B 8 (1996) 229-244.
[33] M. Haruta, H. Sano, Int. J. Hydrogen Energ. 7 (1982) 737-740.
[34] R. Hu, R. Ding, J. Chen, J. Hu, Y. Zhang, Catal. Commun. 21 (2012) 38-41.
[35] G. Saracco, F. Geobaldo, G. Baldi, Appl. Catal. B 20 (1999) 277-288.
[36] Z. Zhong, K. Chen, Y. Ji, Q. Yan, Appl. Catal. A 156 (1997) 29-41.
[37] C.A. da Silva, P.E.V. de Miranda, Int. J. Hydrogen Energy 40 (2015) 10002-10015.
[38] A.C. Terracciano, S.T. De Oliveira, S.S. Vasu, N. Orlovskaya, Exp. Therm. Fluid Sci. 90 (2018) 330-335.