Fe3O4@SiO2@IL‐PVP magnetic nanoparticles: Effective synthesis of spirooxindoles

Iranian Journal of Catalysis

مقاله 3، دوره 11، شماره 2، شهریور 2021، صفحه 125-136   

نوع مقاله: Articles

نویسندگان

Shahla Veysipour؛ Masoud Nasr-Esfahani^* ؛ Zahra Rafiee؛ Behrouz Eftekhari far

Department of Chemistry, Faculty of Science, Yasouj University, Yasouj, 75918-74831, Iran.

چکیده

Various magnetite heterogeneous catalysts for the organic reaction are increasingly recognized while their stability still is a critical challenge. In this regard, SiO₂, ionic liquid (IL), and polyvinyl pyrrolidone (PVP) were applied as a three-layer stabilization system for modifying magnetic Fe₃O₄ to produce Fe₃O₄@SiO₂@IL‐PVP as a novel nanocatalyst. The Fe₃O₄@SiO₂@IL‐PVP as stabilized heterogeneous catalysts were utilized in a robust, and environmentally friendly strategy for the preparation of the spirooxindole derivatives by the one-pot condensation of isatin, malononitrile, and 1,3-dicarbonyl in a water solvent. The proposed method revealed a high yield spirooxindole derivatives preparation (99%) at short reaction times (1.0 min), low catalyst mass (0.002 g), and satisfactory temperature (30 °C) which confirm the lack of any tedious challenge and promising applicability and reusability. This work introduces a rational core-shell nanosystem design with a facile and novel construction strategy to arrive at nonexquisite metal-based composite catalysts with superior catalytic proficiency and prominent long-term stability.

کلیدواژه‌ها

Magnetic nanoparticles؛ Spirooxindoles؛ Green synthesis؛ Fe3O4@SiO2@IL‐PVP nanocomposite؛ Reusable catalyst

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