Hirshfeld surface analysis of solid-state synthesized NiFe2O4 nanocomposite and application of it for photocatalytic degradation of Water pollutant dye

International Journal of Nano Dimension

مقاله 2، دوره 13، شماره 2، مرداد 2022، صفحه 155-167   

نوع مقاله: Reasearch Paper

شناسه دیجیتال (DOI): 10.22034/ijnd.2022.686624

نویسندگان

Alireza Hakimyfard^{* 1}؛ Shahin Khademinia²

¹Department of Physics, Faculty of Science, Jundi-Shapur University of Technology, Dezful, Iran.

²Department of Inorganic Chemistry, Faculty of Chemistry, Semnan University, Semnan, Iran.

چکیده

The present work reports the Hirshfeld surface analysis and photocatalytic performance of NiFe₂O₄ nanomaterial. Hirshfeld surface analysis was performed to understand the interaction properties of the NiFe₂O₄ compound. The active sites including π-π interactions are studied by the analysis. The Hirshfeld data showed that the two wings in the O…O and O…Ni diagrams are created by short contacts of O…O, and O…Ni which causes O―O…π and O―Ni…. π interactions. The interactions cover the surfaces with values of 8.8% and 9.4%, respectively. Nanostructured NiFe₂O₄ powder was used as a photocatalyst to degrade Malachite Green (MG) waste water pollutant dye under visible light irradiation. The optimized conditions for the degradation of a 100 mL of 80 ppm MG aqueous solution are 0.03 mL H₂O₂, 0.038 g catalyst, and 45 min reaction time. The degradation yield at the optimized conditions under visible light irradiation was 95 %. The light source was a white color fluorescent lamp with the 40 W power and light intensity of 1.34 W/m² measured by a digital lux meter.

کلیدواژه‌ها

Dye Degradation؛ Hirshfeld Surface Analysis؛ Malachite Green؛ Nanophotocatalyst؛ Nickel Ferrite

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