Enhancement of ruthenium-promoted Co/CNT nanocatalyst performance using microemulsion technique

International Journal of Industrial Chemistry

دوره 5، شماره 1، خرداد 2014، صفحه 1-14

نوع مقاله: research article

شناسه دیجیتال (DOI): https://doi.org/10.1186/2228-5547-5-1

نویسندگان

Ahmad Tavasoli^{* 1}؛ Somayeh Taghavi²؛ Saber Tabyar²؛ Saba Karimi²

¹School of Chemistry, College of Science, University of Tehran, Tehran, 1417614411, Iran

²School of Chemistry, College of Science, University of Tehran, Tehran, 1513746911, Iran

چکیده

Background
Ruthenium-promoted cobalt nanocatalysts that are supported by carbon nanotubes (CNTs) are prepared using impregnation and microemulsion techniques. Ruthenium loadings were varied from 0 to 1 wt.% while the amount of cobalt was fixed at 15 wt.%. The nanocatalysts were extensively characterized by different methods and their activity and selectivity in Fischer-Tropsch synthesis (FTS) have been assessed in a fixed-bed microreactor. The physicochemical properties and performance of the nanocatalysts were compared with the catalyst prepared by impregnation method.
Results
Very narrow particle size distribution has been produced by the microemulsion technique. According to the transmission electron microscopy, pictures small Co particles (2 to 7 nm) are mostly confined inside the CNTs. Ruthenium increased the percentage reduction of the unpromoted catalyst by a factor of 25. Compared with the catalysts prepared by impregnation, using microemulsion technique with water-to-surfactant ratio of 0.5 which decreased the average cobalt oxide particle sizes to 4.8 nm, the percentage of dispersion is almost doubled and the percentage of reduction is increased by 28.
Conclusions
Addition of ruthenium increased the percentage conversion and C₅⁺ selectivity of the unpromoted catalyst by a factor of 22.6 and 7, respectively. Activity and selectivity were found to be dependent on the catalyst preparation method and water-to-surfactant ratio (as well as on cobalt particle sizes). The percentage of CO conversion and FTS rate increased from 59.09 to 75.05 and 0.291 to 0.372 gr HC/gr cat/h, respectively, while the C₅⁺ liquid hydrocarbons selectivity decreased slightly.

کلیدواژه‌ها

Fischer-Tropsch synthesis؛ Cobalt؛ Ruthenium؛ Microemulsion؛ Particle size