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Photo-curing kinetics of hydroxyethyl acrylate (HEA): synergetic effect of dye/amine photoinitiator systems | ||
| International Journal of Industrial Chemistry | ||
| دوره 11، شماره 1، خرداد 2020، صفحه 1-9 | ||
| نوع مقاله: research article | ||
| شناسه دیجیتال (DOI): https://doi.org/10.1007/s40090-019-00197-7 | ||
| نویسندگان | ||
| Nouria Bouchikhi* 1، 2؛ Manel Bouazza2؛ Salah Hamri1، 2؛ Ulrich Maschke3؛ Djahida Lerari1؛ Faycal Dergal1؛ Khaldoun Bachari1؛ Lamia Bedjaoui-Alachaher2 | ||
| 1Centre de Recherche Scientifique et Technique en Analyses Physico-chimiques, BP 384, Zone Industrielle Bou-ismail, RP, 42004, Tipaza, Algeria | ||
| 2Laboratoire de Recherche sur les Macromolécules, Faculté des Sciences, Université de Tlemcen, BP119, 13000, Tlemcen, Algeria | ||
| 3Unité Matériaux et Transformations UMET (UMR CNRS N_8207) Bâtiment C6, Université Lille 1-Sciences et Technologies, 59655, Villeneuve d’Ascq, France | ||
| چکیده | ||
| The aim of this study is to examine and evaluate several dye/amine systems as photoinitiators for photopolymerization of 2-hydroxyethyl acrylate (HEA) monomer under visible light conditions. For this purpose, a series of dye/amine photoinitiators were formed using methylene blue (MB) or acridine orange (AO) as photosensitizers, and triethanolamine (TEOA), ethyl 4-(dimethylamino) benzoate (EDMAB), trioctylamine (TOA), and N,N-diméthylallylamine (DMAA) as co-initiators. The photopolymerization kinetic of the HEA monomer in the presence of proposed dye/amine systems was performed using Fourier-transform infrared spectroscopy (FTIR) analysis and the synergetic effect of the dye/amine photoinitiators systems on the photopolymerization efficiency was examined. Interestingly, (MB/EDMAB) system shows the better reactivity with a total conversion of HEA monomer. | ||
| کلیدواژهها | ||
| Dye · Amine · Visible light · Phototransformation · Photopolymerization | ||
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