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Menkiti, Matthew C., Ocheje, Ocholi, Agu, Chinedu M.. (1396). Production of environmentally adapted lubricant basestock from jatropha curcas specie seed oil. نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 8(2), 133-144. doi: https://doi.org/10.1007/s40090-017-0116-1
Matthew C. Menkiti; Ocholi Ocheje; Chinedu M. Agu. "Production of environmentally adapted lubricant basestock from jatropha curcas specie seed oil". نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 8, 2, 1396, 133-144. doi: https://doi.org/10.1007/s40090-017-0116-1
Menkiti, Matthew C., Ocheje, Ocholi, Agu, Chinedu M.. (1396). 'Production of environmentally adapted lubricant basestock from jatropha curcas specie seed oil', نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 8(2), pp. 133-144. doi: https://doi.org/10.1007/s40090-017-0116-1
Menkiti, Matthew C., Ocheje, Ocholi, Agu, Chinedu M.. Production of environmentally adapted lubricant basestock from jatropha curcas specie seed oil. نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 1396; 8(2): 133-144. doi: https://doi.org/10.1007/s40090-017-0116-1

Production of environmentally adapted lubricant basestock from jatropha curcas specie seed oil

International Journal of Industrial Chemistry
دوره 8، شماره 2، شهریور 2017، صفحه 133-144
نوع مقاله: research article
شناسه دیجیتال (DOI): https://doi.org/10.1007/s40090-017-0116-1
نویسندگان
Matthew C. Menkiti* 1، 2؛ Ocholi Ocheje2؛ Chinedu M. Agu2
1Civil, Environmental and Construction Engineering Department, Texas Tech University, Lubbock, TX, USA
2Chemical Engineering Department, Nnamdi Azikiwe University, Awka, Nigeria
چکیده
Jatropha curcas seed oil was studied for the synthesis of trimethylolpropane based biolube basestock via chemical transesterification of Jatropha methyl ester with trimethylolpropane (TMP) using calcium hydroxide catalyst. Reactions temperatures ranged between 80 and 160 °C and methyl esters to TMP mole ratios ranged between 3:1 and 7:1. Product analysis, ester groups and physio-chemical properties were obtained by gas chromatography, Fourier transform infrared spectroscopy and American Society for testing and material standard methods, respectively. Gibbs free energy indicated that the reaction was spontaneous with a second order rate constant of 1.00E−01 (%wt/wt min C)−1 and kinetic energy of 13.57 kJ/mol. Jatropha biolubricant (JBL) had the following properties: viscosity of 39.45 and 8.51 cSt at 40 and 100 °C, respectively; viscosity index of 204, pour point of −12 °C and flash point of 178 °C. Temperature and mole ratio were the main factors that influenced the reaction. JBL properties complied with ISO VG 32 standard and could be applied as lube basestock with minor modifications.
کلیدواژه‌ها
Jatropha curcas؛ Biolubricant؛ Transesterification؛ Trimethylolpropane
آمار
تعداد مشاهده مقاله: 19


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