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Ramalingam, R. Jothi, Radhika, T., Adam, Farook, Dolla, Tarekegn Heliso. (1395). Acetylation of glycerol over bimetallic Ag–Cu doped rice husk silica based biomass catalyst for bio-fuel additives application. نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 7(2), 187-194. doi: https://doi.org/10.1007/s40090-016-0073-0
R. Jothi Ramalingam; T. Radhika; Farook Adam; Tarekegn Heliso Dolla. "Acetylation of glycerol over bimetallic Ag–Cu doped rice husk silica based biomass catalyst for bio-fuel additives application". نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 7, 2, 1395, 187-194. doi: https://doi.org/10.1007/s40090-016-0073-0
Ramalingam, R. Jothi, Radhika, T., Adam, Farook, Dolla, Tarekegn Heliso. (1395). 'Acetylation of glycerol over bimetallic Ag–Cu doped rice husk silica based biomass catalyst for bio-fuel additives application', نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 7(2), pp. 187-194. doi: https://doi.org/10.1007/s40090-016-0073-0
Ramalingam, R. Jothi, Radhika, T., Adam, Farook, Dolla, Tarekegn Heliso. Acetylation of glycerol over bimetallic Ag–Cu doped rice husk silica based biomass catalyst for bio-fuel additives application. نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 1395; 7(2): 187-194. doi: https://doi.org/10.1007/s40090-016-0073-0

Acetylation of glycerol over bimetallic Ag–Cu doped rice husk silica based biomass catalyst for bio-fuel additives application

International Journal of Industrial Chemistry
دوره 7، شماره 2، شهریور 2016، صفحه 187-194
نوع مقاله: research article
شناسه دیجیتال (DOI): https://doi.org/10.1007/s40090-016-0073-0
نویسندگان
R. Jothi Ramalingam* 1؛ T. Radhika2؛ Farook Adam2؛ Tarekegn Heliso Dolla3
1Surfactants research chair, Chemistry department, College of Science, King Saud University, Riyadh, Kingdom of Saudi Arabia
2School of Chemical Sciences, Universiti Sains Malaysia, Penang, 11800, Malaysia
3College of Natural and Computational Sciences, Wolaita Sodo University, Wolaita Sodo, Ethiopia
چکیده
Acetylation of glycerol with acetic acid was carried out over bimetallic silver and copper deposited rice husk silica-alumina like ecofriendly green catalyst. Bio-additive like mono, di and tri acetyl glycerol synthesis from raw glycerol (one of the main product of biodiesel), which are gaining attention as additives for improving petroleum fuel properties towards biofuel additive development applications. Advantage of using bimetallic catalyst for glycerol acetylation due to possible synergistic effect between the metals and it enhances the catalytic conversion and selectivity compared to single metal catalyst. The prepared catalysts were characterised by XRD, FT-IR and TEM. Silver and copper incorporated RHS (rice husk silica)-alumina catalysts are shown higher activity and selectivity towards diacetin (di acetyl glycerol) and triacetins (tri acetyl glycerol) formation by catalytic acetylation of glycerol. Higher conversion (98 %) and good selectivity (51 %) is achieved.
کلیدواژه‌ها
Glycerol؛ Acetylation؛ Silver؛ Rice husk silica؛ Monoacetin؛ Triacetin؛ Biodiesel
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تعداد مشاهده مقاله: 22


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