Removal of Toxic Congo Red Dye from Aqueous Solution Using a Graphene Oxide/Poly (Acrylamide-Acrylic acid) Hydrogel: Characterization, Kinetics and Thermodynamics Studies

Journal of Chemical Health Risks

دوره 12، شماره 4، اسفند 2022، صفحه 609-619   

نوع مقاله: Original Article

شناسه دیجیتال (DOI): 10.22034/jchr.2022.690303

نویسندگان

Rafid Q. Kmal¹؛ Aseel M. Aljeboree^{* 2}؛ Layth S. Jasim¹؛ Nadher D. Radia¹؛ Ayad F. Alkaim²

¹Department of Chemistry, College of Education, University of Al-Qadisiyah, Diwaniya, Iraq

²Department of Chemistry, College of Sciences for Girls, University of Babylon, Hilla, Iraq

چکیده

This research studies the removal of textile dye (Congo red (CR)) from aqueous solution via using low-cost adsorbent prepared from GO/P (AA-co-AM) composite. Batch adsorption experiments were conducted to estimate the influence of several factors like pH solution, the concentration of CR dye, equilibrium time, adsorbent amount, and temperature solution. The top result correlation was found via the Langmuir model, and the best adsorption efficiency was 52.55 mg g^–1 for CR dye. Thermodynamic studies appear that the adsorption of CR dye was feasible, endothermic, and spontaneous. Through the results, the prepared surface has very high efficiency in removing textile dyes and is environmentally friendly, inexpensive.

کلیدواژه‌ها

Adsorption؛ Dye, Removal؛ Pollution؛ Kinetic؛ Isotherm؛ Thermodynamic

مراجع

1. Gamoudi S., Srasra E., 2019. Adsorption of organic dyes by HDPy+-modified clay: effect of molecular structure on the adsorption. Journal of Molecular Structure. 1193, 522-531.
2. Wenyan Jiang L.Z., Xiaoming G., Mei Y., Yiwen L., Yijun W., Yousen Zh., Guangtao W., 2019. Adsorption of cationic dye from water using an iron oxide/activated carbon magnetic composites prepared from sugarcane bagasse by microwave method. Environmental Technology. 2. DOI: 10.1080/09593330.
3. Hadi Z.A., Aljeboree A.M., Alkaim A.F., 2014 Adsorption of a cationic dye from aqueous solutions by using waste glass materials: Isotherm and thermodynamic studies. International Journal of Chemical Sciences. 12. 1273-1288.
4. Yahya A., Faleh N.D.R., 2021 Removal of Metformin hydrochloride from Aqueous Solutions by using Carboxymethyl cellulose-g-poly(acrylic acid-co-acrylamide) Hydrogel: Adsorption and Thermodynamic Studies. IOP Conf. Series: Earth and Environmental Science. 790, 012062.
5. Yongde Liu Y.C., Yahui Shi Dongjin W., Jing Ch., Shuhu X., 2019 Adsorption of toxic dye Eosin Y from aqueous solution by clay/carbon composite derived from spent bleaching earth. Journal of Hazardous Materials. 1, 4656-5544.
6. Aljeboree A.M., Alkaim A.F., 2019. Removal of Antibiotic Tetracycline (TCs) from aqueous solutions by using Titanium dioxide (TiO₂) nanoparticles as an alternative material. Journal of Physics: Conf. Series. 1294, 052059.
7. Bahareh Tanhaei A.A., Evgenia I., Mika S., 2020 Efficient carbon interlayed magnetic chitosan adsorbent for anionic dye removal: Synthesis, characterization and adsorption study. International Journal of Biological Macromolecules. 164, 3621-3631.
8. Ayad F. Alkaim A.M.A., 2020 Adsorption and Photocatalytic Degradation of Pharmaceutical Amoxicillin using TiO₂ Nanoparticles in Aqueous Solutions: Oxidative Coupling as Spectrophotometric Method International Journal of Advanced Science and Technology. 29, 5480 - 5487
9. Kamil A.M., Mohammed H.T., Alkaim A.F., Hussein F.H., 2016 Adsorption of Congo red on multiwall carbon nanotubes: Effect of operational parameters. Journal of Chemical and Pharmaceutical Sciences. 9, 1128-1133.
10. Waleed K. Abdulsahib S.H.G., Nadher D. R., Layth S.J. 2020 New Approach for Sulfadiazine Toxicity Management using Carboxymethyl Cellulose Grafted Acrylamide Hydrogel. International Journal of Drug Delivery Technology. 10. 259-264.
11. Layth S. Jasim A.M.A., 2021 Removal of Heavy Metals by Using Chitosan/ Poly (Acryl Amide-Acrylic Acid)Hydrogels: Characterization and Kinetic Study NeuroQuantology. 19, 31-37.
12. Yasin A.S., Kim D.H, Lee K., 2021 One-pot synthesis of activated carbon decorated with ZnO nanoparticles for capacitive deionization application. Journal of Alloys and Compounds. 870. 159422.
13. Medhat A., Maghrabi H., Abdelghany A., Menem N., Raynaud P., Moustafa Y., Elsayed M., Nada A., 2021 Efficiently activated carbons from corn cob for methylene blue adsorption. Applied Surface Science Advances. 2, 100037.
14. Nadher D. Radhy L.S.J., 2019. Synthesis of Graphene Oxide/Hydrogel Composites and Their Ability for Efficient Adsorption of Crystal Violet. J Pharm Sci Res. 11. 456-463.
15. Layth S.J., Hayder O.J., 2018. Synthesis and Characterization of Poly (Acryl Amide - Maleic Acid) Hydrogel: Adsorption Kinetics of a Malachite Green from Aqueous Solutions Eurasian Journal of Analytical Chemistry. 13. em74.
16. Aljeboree A.M., Ayad A.N.A., ALkaim F., 2019 Removal of Pharmaceutical Amoxicillin drug by using (CNT) decorated Clay/ Fe₂O₃ Micro/Nanocomposite as effective adsorbent: Process optimization for ultrasound‐assisted adsorption. International Journal of Pharmaceutical Research. 11. 80-86.
17. Zaied A. Mosaa A.T.B., Aljeboree A. M, Ayad F.A., 2019. Adsorption and removal oftextile dye (methylene Blue MB) from aqueous solution by activated carbon as a model (apricot stone source waste)  of plant role in environmental enhancement. Plant Archives. 19, 910-914.
18. Abbas N., 2019. Synthesis and Characterization of Poly (CH/AA-co-AM) Composite: Adsorption and Thermodynamic Studies of Benzocaine on from Aqueous Solutions International Journal of Drug Delivery Technology. 9, 558-562.
19. Aljeboree A.M., 2019 Removal of Vitamin B6 (Pyridoxine) Antibiotics Pharmaceuticals From Aqueous Systems By ZnO. International Journal of Drug Delivery Technology. 9, 125-129.
20. Águila-Carrasco A.J.D., 2019 Effect of phenylephrine on static and dynamic accommodation. Journal of Optometry. 12, 30-37.
21. Secondes M.F.N., Ballesteros Jr V.N., Belgiorno F.V., 2014 Adsorption of emerging contaminants enhanced by ultrasound irradiation. Sustain Environ Res. 24. 349-355.
22. Ahlam M.F., 2013 Equilibrium and kinetic studies of cadmium(II) and lead(II) ions biosorption onto Ficus carcia leaves. International Journal of Industrial Chemistry. 4, 24.
23. Ghaedi M., Sadeghian B., Pebdani A.A., Sahraei R., Daneshfar A., Duran C., 2012 Kinetics, thermodynamics and equilibrium evaluation of direct yellow 12 removal by adsorption onto silver nanoparticles loaded activated carbon. Chem Eng J. 187, 133-141.
24. Chiban M.G.C., Lehutu G., Sinan F., 2016 Equilibrium and thermodynamic studies for the removal of As(V) ions from aqueous solution using dried plants as adsorbents. Arabian Journal of Chemistry. 9, S98.
25. Jasim Layth S., Hayder O.J., 2018 Synthesis and Characterization of Poly (Acryl Amide - Maleic Acid) Hydrogel: Adsorption Kinetics of a Malachite Green from Aqueous Solutions. Eurasian Journal of Analytical Chemistry. 13, 74.
26. Langmuir I., 1918. Adsorption of gases on plain surfaces of glass mica platinum. J Am Chem Soc. 40. 1361-1403.
27. Adeyemo A.A., Adeoye I.O., Bello O.S., 2017 Adsorption of dyes using different types of clay: a review. Appl Water Sci. 7. 543-568.
28. Ayad F.A., 2020 White Marble as an Alternative Surface for Removal of Toxic Dyes (Methylene Blue) from Aqueous Solutions International Journal of Advanced Science and Technology. 29, 5470 - 5479.
29. Lagergren S., 1898 About the theory of so-called adsorption of soluble substances. K. Sven. Vetenskapsakad. Handl. 24.
30. Ho Y.S., McKay G., 1998 orption of dye from aqueous solution by peat. S Chem Eng J. 70, 115.
31. Acero J.L., Benitez F.J., Real F.J., Roldan G., 2010. Kinetics of aqueous chlorination of some pharmaceuticals and their elimination from water matrices. Water Res. 44. 4158-4170.
32. Kalithasan Natarajan H.C., Bajaj Rajesh J.T., 2016 Photo catalytic efficiency of bismuth oxyhalide (Br, Cl and I) nanoplates for RhB dye degradation under LED irradiation. Journal of Industrial and Engineering Chemistry. 34 146-156.