Study of Structural and Optical Properties of 2D Organic–InorganicPerovskites based on Triphenylphosphine

Journal of Applied Chemical Research

دوره 16، شماره 3، مهر 2022، صفحه 48-56   

نوع مقاله: Original Article

نویسندگان

Soghra Mirershadi^{* 1}؛ Saeid Maleki²

¹Department of Engineering Sciences, Faculty of Advanced Technologies, University of MohagheghArdabili, Namin, Iran

²Department of Chemistry, Faculty of Sciences, University of Mohaghegh Ardabili, Ardabil, Iran

چکیده

In recent years, three-dimensional hybrid perovskites (CH₃NH₃PbX₃) with X=I, Br, and Cl have raised great attention due to their facile production methods and encouraging energy conversion efficiency in solar cells based on perovskite. A majority of the systematic studies on the regulation of the band gap in the family of organolead halide perovskites have focused on changing thecompositions of halogens. However, organic portion can provide a wider structural diversity in band gap and dimensionality in perovskite structures.Thus, Investigation of the structural and optical properties of organic-inorganic perovskitesby changing the organic portion seems to be necessary. The main focus of this work is the tetraphenylphosphonium substitutions at the organic portionin the hybrid perovskite structures.In this paper, fabrication of organic−inorganic hybrid perovskite TPP₂PbX₄, (TPP = P(C₆H₅)₄; X = Cl), is reported.Thesynthesis method, crystal structure, and optical behavior of the synthesized perovskiteswere investigated. The organic cation effect on the optical properties and bandgap tuning were studied experimentally. The remarkable electronics and optical properties of 2D perovskite structurescould provide a different perspective and suggest the potential of these materials for photonics applications.
 

کلیدواژه‌ها

2D layered hybrids؛ Perovskites؛ Tetraphenylphosphonium؛ Bandgap tuning

مراجع

[1]. D. Bi, W. Tress, M. I. Dar, P. Gao, J. Luo, C. Renevier,K. Schenk, A. Abate, F. Giordano, J. P.
Baena, J. D. Decoppet, S. M. Zakeeruddin, M. K. Nazeeruddin, M. Grätzel, A.Hagfeldt, Sci. Adv.,
2, e1501170 (2016).
[2]. G. Pacchioni, Nat.Rev.Mater., 6, 108 (2021).
[3]. S. A. Veldhuis, P. P. Boix, N. Yantara, M. Li, T. C. Sum, N. Mathews, S. G. Mhaisalkar, Adv.
Mater., 28, 6804 (2016).
[4]. L. Dou, Y. Yang, J. You, Z. Hong, W.H. Chang, G. Li, Y. Yang,Nat. Commun.,5, 5404 (2014).
[5]. J. S. Manser, J. A. Christians, P. V. Kamat,Chem. Rev., 116, 12956 (2016).
[6]. B. Saparov, D. B. Mitzi,Chem. Rev., 116, 4558 (2016).
[7]. C. Li, H. Wang, F. Wang, T. Li, M. Xu, H. Wang, Z. Wang, X. Zhan, W. Hu, L. Shen, Light Sci.
Appl., 9, 31 (2020).
[8]. M. H. Soltani, A. Reyhani, A. Taherkhani, S. Mirershadi, S. Z. Mortazavi, J Mater Sci: Mater.
Electron., 32, 15675 (2021).

[9]. F. Ebadi, B. Yang, Y. Kim,R. Mohammadpour, N. Taghavinia, A. Hagfeldt,W. Tress, J. Mater.
Chem. A.,9, 13967 (2021).
[10]. S. D. Stranks, H. J. Snaith,Nat. Nanotechnol., 10, 391(2015).
[11]. A. H. Slavney, R. W. Smaha, I. C. Smith, A. Jaffe, D. Umeyama, H. I. Karunadasa, Inorg.
Chem., 56, 46(2017).
[12]. T. T. Tran, J. R. Panella, J. R. Chamorro, J. R. Morey, T. M. McQueen, Mater. Horiz., 4, 688
(2017).
[13]. S. Mirershadi, A. Javad, S.A. Ahmadi-Kandjani, J. Theor. Appl. Phys., 13, 133 (2019).
[14]. J. H. Heo, S. H. Im, J. H. Noh, T. N. Mandal, C. S. Lim, J. A. Chang, Y. H. Lee, H. I. Kim, A.
Sarkar, M. K. Nazeeruddin, M. Grätzel, S. I. Seok, Nat. Photonics., 7, 486 (2013).
[15]. S. Yakunin, M. Sytnyk, D. Kriegner, S. Shrestha, M. Richter, G. J. Matt, H. Azimi, C. J.
Brabec, J. Stangl, M. V. Kovalenko, W. Heiss, Nat. Photonics.,9, 444 (2015).
[16]. C. C. Stoumpos, C. D. Malliakas, J. A. Peters, Z. Liu, M. Sebastian, J. Im, T. C. Chasapis, A.
C. Wibowo, D. Y. Chung, A. J. Freeman, B. W. Wessels, M. G. Kanatzidis, Cryst. Growth Des., 13,
2722 (2013).
[17]. N. Kawano, M. Koshimizu, Y. Sun, N. Yahaba, Y. Fujimoto, T. Yanagida, K. Asai. J. Phys.
Chem. C., 118, 9101 (2014).
[18]. L. A. Boatner, D. Wisniewski, J. S. Neal, J. O. Ramey, J. A. Kolopus, B. C. Chakoumakos, M.
Wisniewska, R. Custelcean, Appl. Phys. Lett., 93, 244104 (2008).
[19]. S. A. Vaughn, B. C. Chakoumakos, R. Custelcean, J. O. Ramey, M. D. Smith, L. A. Boatner,
H. C. Loye, Inorg. Chem., 51, 10503 (2012).
[20]. S. Mirershadi, S. Ahmadi-Kandjani, M. S. Zakerhamidi,S. Z. Mortazavi, Iran. J. Sci. Technol.
Trans. Sci.,41, 873 (2017).
[21]. H. Shi, M. H. Du, Phys. Rev. Appl., 3, 054005 (2015).
[22]. P. V. Kamat, Chem. Rev., 93, 267 (1993).
[23]. K. M. McCall, C. C, Stoumpos, S. S. Kostina, M. G. Kanatzidis, B. W. Wessels, Chem. Mater.,
29, 4129 (2017).
[24]. B. Saparov, F. Hong, J. P. Sun, H. S. Duan, W. Meng, S. Cameron, I. G. Hill, Y. Yan, D. M.
Mitzi, Chem. Mater., 27, 5622 (2015).
[25]. A. L. Allred, Electronegativity values from thermochemical data. J. Inorg. Nucl. Chem., 17,
215 (1961).

[26]. J. Zaanen, G. A. Sawatzky, J. W. Allen,Phys. Rev. Lett., 55, 418 (1985).
[27]. L. Guo, H. Liu, Y. Dai, S. Ouyang, J. Phys. Chem. Solids, 7, 68, 1663 (2007).
[28]. A. Aisha, A. Naureen, A. Polyakov, P. Rudolf, APL. mater, 6, 114206 (2018).

[29]. G. Alvarez, A. Conde-Gallardo, H. Montiel, R. Zamorano,J. Magn. Magn. Mater. 401, 196
(2016).
[30]. H. Tavakkoli, A. Ghaemi, M.Mostofizadeh, Int. J. Sci. Res. 2, 340 (2014).
[31]. N. Kitazawa, Y. Watanabe, J. Phys. Chem. Solids., 71, 797(2010).
[32]. L. Liang, J. Zhang, Y. Zhou, J. Xie, X. Zhang, M. Guan, B. Pan, Y. Xie, Sci.
Rep.,1936,1(2013).
[33]. L. Guo, H. Liu, Y. Dai, Sh. Ouyang, J. Phys. Chem. Solids., 68, 1663 (2007).