The application of Flame Atomic Absorption Spectrometry to evaluate Lead (II) in Vegetable Samples after Its Preconcentration by SA-DLLME

Journal of Chemical Health Risks

دوره 13، شماره 2، شهریور 2023، صفحه 357-366   

شناسه دیجیتال (DOI): 10.22034/jchr.2022.693103

نویسنده

Sajda .S. Affat^*

Department of Chemistry, College of Science, University of Thi-Qar, Iraq

چکیده

In this paper, a new and environmentally friendly approach has been developed to determine the levels of lead in plant samples. To preconcentrate the lead ion, SA-DLLME (surfactant-assisted dispersive liquid-liquid micro-extraction) was used in the study of flame atomic absorption spectrometry (FAAS). The influence of the following analytical parameters on the quantitative recoveries of lead was studied: pH, type and amount of the extraction solvent, type and amount of the dispersing solvent, type and amount of the surfactant, centrifugation time and rate, amount of (APDC), sample volume and amount of matrix. The approach was validated using vegetable samples. The approach offered a (LOD) of 0.28 μg l^-1, (LOQ) of 0.933 μg l^-1, (RSD) of 1.2-4.3%, (EF) of 85, PF of 30, and ER% of (100.6-102.1)%.

کلیدواژه‌ها

Lead ion؛ SA-DLLME؛ Recovery؛ Non-ionic surfactant؛ Matrix؛ Vegetable samples

مراجع

1. Schütz A., Olsson M., Jensen A., Gerhardsson L., Börjesson J., Mattsson S., Skerfving S., 2005. Lead in finger bone, whole blood, plasma and urine in lead-smelter workers: extended exposure range. International Archives of Occupational and Environmental Health. 78(1), 35-43.
2. García-Lestón J., Méndez J., Pásaro E., Laffon B., 2010. Genotoxic impacts of lead: an updated review. Environment International. 36(6), 623-636.
3. Lepper T.W., Oliveira E., Koch G.D.W., Berlese D.B., Feksa L.R., 2010. Lead inhibits in vitro creatine kinase and pyruvate kinase activity in brain cortex of rats. Toxicology in Vitro. 24(3), 1045-1051.
4. Klaassen C.D. ed., 2013. Casarett and Doull's toxicology: the basic science of poisons (Vol. 1236, p. 189). New York: McGraw-Hill.
5. Afatt S.S., Mahdi H.A., 2012. Synthesis and Characterization of a new Schiff Base {N-(2-{[(4-bromophenyl) imino] methyl} phenyl) acetamide} and its complexes with some transition metal. Journal of College of Education for Pure Science. 2(4), 110-117.
6. Soylak M., Temeltas A., 2016. Solid phase extraction of Pb (II) and Cd (II) as 2, 9 dimethyl-4, 7-diphenyl-1, 10-phenanthroline chelates on activated carbon cloth in environmental samples and their determination by flame atomic absorption spectrometry. International Journal of Environmental Analytical Chemistry. 96(9), 862-871.
7. Arain S.S., Kazi T.G., Arain J.B., Afridi H.I., Brahman K.D., 2014. Preconcentration of toxic elements in artificial saliva extract of different smokeless tobacco products by dual-cloud point extraction. Microchemical Journal. 112, 42-49.
8. Lertlapwasin R., Bhawawet N., Imyim A., Fuangswasdi S., 2010. Ionic liquid extraction of heavy metal ions by 2-aminothiophenol in 1-butyl-3-methylimidazolium hexafluorophosphate and their association constants. Separation and Purification Technology. 72(1), 70-76.
9. Ebrahimzadeh H., Behbahani M., 2017. A novel lead imprinted polymer as the selective solid phase for extraction and trace detection of lead ions by flame atomic absorption spectrophotometry: synthesis, characterization and analytical application. Arabian Journal of Chemistry. 10, 2499-2508.
10. Peng G., He Q., Zhou G., Li Y., Su X., Liu M., Fan L., 2015. Determination of heavy metals in water samples using dual-cloud point extraction coupled with inductively coupled plasma mass spectrometry. Analytical Approachs. 7(16), 6732-6739.
11. Affat S.S., Al-Shamkhawy S., 2018. Synthesis and Characterization of a 6, 6'-((1E, 1'E)-(1, 2-phenylenebis (azanylylidene)) bis (methanylylidene)) bis (2-methoxy-3-((6-methoxybenzo [d] thiazol-2-yl) diazenyl) phenol): as a highly sensitive reagent for determination cadmium (II) ion in the real Samples. International Journal of Pharmaceutical Research. 10(4), 480-497.
12. Sorouraddin S.M., Farajzadeh M.A., Ghorbani M., 2018. Development of a green effervescence-assisted dispersive liquid–liquid microextraction approach using a home-made tablet disperser for trace analysis of Cd(II) and Pb(II). International Journal of Environmental Analytical Chemistry. 98(2), 182-195.
13. Rezaee M., Yamini Y., Faraji M., 2010. Evolution of dispersive liquid–liquid microextraction approach. Journal of Chromatography A. 1217(16), 2342-2357.
14. de Oliveira F.A., de Abreu A.T., de Oliveira Nascimento N., Froes-Silva R.E.S., Antonini Y., Nalini Jr H.A., de Lena J.C., 2017. Evaluation of matrix impact on the determination of rare earth elements and As, Bi, Cd, Pb, Se and In in honey and pollen of native Brazilian bees (Tetragonisca angustula–Jataí) by Q-ICP-MS. Talanta. 162, 488-494.
15. de Oliveira R.M., Antunes A.C.N., Vieira M.A., Medina A.L., Ribeiro A.S., 2016. Evaluation of sample preparation approachs for the determination of As, Cd, Pb, and Se in rice samples by GF AAS. Microchemical Journal. 124, 402-409.
16. Parson R.G., 1963. Synthesis and extraction studies of calix[4]-Crown-4 oxime derivatives. Journal of the American Chemical Society. 85(22), 3533-3539.
17. Nalawade R.A., Nalawade A.M., Kamble G.S., Anuse M.A., 2015. Rapid, synergistic extractive spectrophotometric determination of copper (II) by using sensitive chromogenic reagent N ″, N ″′-bis [(E)-(4-fluorophenyl) methylidene] thiocarbonohydrazide. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 146, 297-306.
18. Hogarth G., 2005. Transition metal dithiocarbamates: 1978–2003. Progress in Inorganic Chemistry. 53, 71-561.
19. Shrivas K., Dewangan K., Ahmed A., 2016. Surfactant-based dispersive liquid–liquid microextraction for the determination of zinc in environmental water samples using flame atomic absorption spectrometry. Analytical Approachs. 8(27), 5519-5525.
20. Acar O., 2001. Determination of cadmium and lead in biological samples by Zeeman ETAAS using various chemical modifiers. Talanta. 55(3), 613-622.
21. Shemirani F., Baghdadi M., Ramezani M., Jamali M.R., 2005. Determination of ultra trace amounts of bismuth in biological and water samples by electrothermal atomic absorption spectrometry (ET-AAS) after cloud point extraction. Analytica Chimica Acta. 534(1), 163-169.
22. Durukan I., Soylak M., Dogan M., 2013. Enrichment and Separation of Fe (III), Mn (II), Ni (II), and Zn (II) as Their Congo Red Chelates on Multiwalled Carbon Nanotube(MWCNT) Disk in Food and Water Samples. Atomic Spectroscopy. 34(1), 20-25.
23. Zhang C., Wang Y., Cheng X., Xia H., Liang P., 2011. Determination of Cadmium and Lead in Human Teeth Samples Using Dispersive Liquid‐liquid Microextraction and Graphite Furnace Atomic Absorption Spectrometry. Journal of the Chinese Chemical Society. 58(7), 919-924.
24. Arpa Ç., Aridaşir I., 2018. A approach to determination of lead ions in aqueous samples: ultrasound-assisted dispersive liquid-liquid microextraction approach based on solidification of floating organic drop and back-extraction followed by FAAS. Journal of Analytical Approachs in Chemistry. https://doi.org/10.1155/2018/8951028.
25. Afzali D., Fayazi M., Favi A., 2013. Displacement-dispersive liquid-liquid microextraction based on solidification floating organic drop trace amounts of lead in water sample prior to flame atomic absorption spectrometry determination. Journal of the Chilean Chemical Society. 58(1), 1593-1596.
26. Duran A., Soylak M., Tuncel S.A., 2008. Poly (vinyl pyridine-poly ethylene glycol methacrylate-ethylene glycol dimethacrylate) beads for heavy metal removal. Journal of Hazardous Materials. 155(1-2), 114-120.
27. Alothman Z.A., Habila M.A., Yilmaz E., Warad I., Soylak M., 2015. Lead preconcentration as rac-(E, E)-N, N′-bis (2-chlorobenzylidene) cyclohexane-1, 2-diamine complexes from water and tobacco samples by dispersive liquid-liquid microextraction. Journal of Analytical Chemistry. 70(6), 691-695.
28. WHO/FAO, 1999. Expert committee on food additives, summary and conclusions. In 53rd meeting, Rome, Italy.
29. M Radwan M.A., Salama A.K., 2006. Market basket survey for some heavy metals in Egyptian fruits and vegetables. Food and Chemical Toxicology. 44(8), 1273-1278.
30. Shirkhanloo H., Sedighi K., Zavvar Mousavi H., 2014. Determination of trace amount of lead in industrial and municipal effluent water samples based on dispersive liquid-liquid extraction. Journal of the Mexican Chemical Society. 58(2), 137-141.