Preparation and investigation of M-MWCNT nanocomposite by hydrothermal method for Pb(II) ions adsorption

International Journal of Nano Dimension

مقاله 5، دوره 13، شماره 4، بهمن 2022، صفحه 387-396   

نوع مقاله: Reasearch Paper

شناسه دیجیتال (DOI): 10.22034/ijnd.2022.1962696.2157

نویسندگان

Mojtaba Zabihi¹؛ Alireza Motavalizadekakhky^{* 2، 3}؛ Maryam Omidvar^{* 4}؛ Rahele Zhiani^{2، 5}؛ Seyed Mohammad Mahdi Nouri⁶؛ Hamid Heydarzadeh Darzi⁶

¹Department of Chemical Engineering, Neyshabur Branch, Islamic Azad University, Neyshabur, Iran.

²Department of Chemistry, Neyshabur Branch, Islamic Azad University, Neyshabur, Iran.

³Avdanced Research Center of Chemistry Biochemistry & Nanomaterial, Neyshabur Branch, Islamic Azad University, Neyshabur, Iran.

⁴Department of Chemical Engineering, Quchan Branch, Islamic Azad University, Quchan, Iran.

⁵New Materials Technology and Processing Research Center, Department of Chemistry, Neyshabur Branch,Islamic Azad University, Neyshabur, Iran.

⁶Chemical Engineering Department, Hakim Sabzevari University, Sabzevar, Iran.

چکیده

In this present work, MWCNTs modified NiFe₂O₄ NPs (M-MWCNT) were successfully fabricated based on a hydrothermal route, and then utilized to Pb(II) sorption from an aqueous solution. The M-MWCNT was characterized and analyzed by SEM, TEM, FTIR, XRD, and VSM techniques. TEM image demonstrated that the size of NiFe₂O₄ nanoparticles in the structure of MWCNT was 20 nm. VSM results indicated that the M-MWCNT with saturation magnetization (Ms) value of  7 emu/g would have a fast magnetic response. According to X-ray data the average crystal sizes of the pure NiFe₂O₄ and M-MWCNT are 21.62 and 7.25 nm, respectively. The sorption kinetics, isotherms, thermodynamic and regeneration performance for lead ((Pb(II)) ions were evaluated. The M-MWCNT can effectively remove Pb(II) from aqueous solution at optimum pH of 5.5. Based on the Langmuir model, the maximum saturated adsorbed amount (q_max) of Pb(II) was up to 85.12 mg/g. The kinetic characteristic was appropriate for pseudo 1^st order model expression, and the isothermal characteristic can be described via Longmuir model. The data obtained from the thermodynamic study show that the Pb(II) sorption using M-MWCNT nanocomposite was a spontaneous, exothermic and physisorption process with a good regeneration performance.

کلیدواژه‌ها

NiFe2O4NPs؛ Nanocomposite؛ MWCNT؛ Lead (II) sorption؛ qmax

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