CO Hydrogenation over functionalized AlMCM-41 materials and ZSM-11/5 zeolites as catalysts

Iranian Journal of Catalysis

مقاله 6، دوره 12، شماره 3، آذر 2022، صفحه 337-352   

نوع مقاله: Articles

شناسه دیجیتال (DOI): 10.30495/ijc.2022.1956221.1928

نویسندگان

B. Smili^{* 1}؛ M. Sakmeche²؛ A. Belhakem³؛ L. Belgacem⁴؛ C. Tabti³

¹Laboratory of Energy Environment and Information System (LEEIS), Department of Material Sciences, Faculty of Sciences and Technology, University of Adrar, National Highway No. 06. Adrar 01000, Algeria.

²Laboratory of Saharan natural resources (LRNS), Department of hydrocarbons and renewable energies, Faculty of Science and Technology. University of Adrar, National High way No. 06. Adrar 01000, Algeria.

³Department of Chemistry, University of Mostaganem, B.P 1001, 27000 Mostaganem, Algeria

⁴Research center in industrial technologies CRTI, Cheraga 16014, Algiers, Algeria

چکیده

We studied the reaction in which carbon monoxide is converted to hydrocarbons, and investigated the behaviors and the combination system of catalysts exchanged with platinum and ammonium ions. Experiments were conducted at 1.2 MPa, 523K, and CO/H₂=1 ratio. The structure and the texture of the catalysts, assessed by XRD, BET/BJH, and SEM, exhibited a microporosity for ZSM-5/11 and a micro/mesoporosity for AlMCM-41, which implies a direct effect on the catalytic properties of these materials. The conversions obtained were 60%, 55%, and 50% for Ptⁿ⁺/H⁺-catalysts, Pt^n+-catalysts, and H⁺-catalysts respectively. Such conversions could be attributed to the good acidity resulting from the simultaneous presence of Ptn⁺/H⁺ at different oxidation states of platinum, which was revealed by XANES PtL_III analysis, and their uniform dispersion within the inner surface and its grain size average conducted by the titration of adsorbed H₂-O₂. FTIR analysis showed a better distribution of acid sites for bi-exchanged catalysts over mono-exchanged ones, which resulted in a good catalytic activity. These results suggest a strong correlation between the high selectivity of light hydrocarbon products, the ions, and the catalyst types. These differences depended mainly on the facility of forming different products, such as n/iso-alkanes and alkenes. Skeletal isomerization was the main transformation observed on exchanged catalysts, particularly those with Ptⁿ⁺/H⁺ ions. A deactivation process of catalysts, versus time-on-stream, begins after 70 minutes, especially for combined exchanged materials.

کلیدواژه‌ها

AlMCM-41 and ZSM 5/11 Materials؛ structure and texture؛ Acidity؛ Pt+/H+ function؛ carbon monoxide hydrogenation

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