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Thaninki, Leena Vinolia, Samson Nesaraj, Arputharaj, Arunkumar, Manasai. (1401). Facile wet chemical synthesis and characterization of zinc doped gadolinium oxide nanoparticles for enhanced photodegradation of Rhodamine B dye under illumination of UV light. نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 12(3), 315-336. doi: 10.30495/ijc.2022.1948621.1904
Leena Vinolia Thaninki; Arputharaj Samson Nesaraj; Manasai Arunkumar. "Facile wet chemical synthesis and characterization of zinc doped gadolinium oxide nanoparticles for enhanced photodegradation of Rhodamine B dye under illumination of UV light". نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 12, 3, 1401, 315-336. doi: 10.30495/ijc.2022.1948621.1904
Thaninki, Leena Vinolia, Samson Nesaraj, Arputharaj, Arunkumar, Manasai. (1401). 'Facile wet chemical synthesis and characterization of zinc doped gadolinium oxide nanoparticles for enhanced photodegradation of Rhodamine B dye under illumination of UV light', نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 12(3), pp. 315-336. doi: 10.30495/ijc.2022.1948621.1904
Thaninki, Leena Vinolia, Samson Nesaraj, Arputharaj, Arunkumar, Manasai. Facile wet chemical synthesis and characterization of zinc doped gadolinium oxide nanoparticles for enhanced photodegradation of Rhodamine B dye under illumination of UV light. نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 1401; 12(3): 315-336. doi: 10.30495/ijc.2022.1948621.1904

Facile wet chemical synthesis and characterization of zinc doped gadolinium oxide nanoparticles for enhanced photodegradation of Rhodamine B dye under illumination of UV light

Iranian Journal of Catalysis
مقاله 5، دوره 12، شماره 3، آذر 2022، صفحه 315-336    اصل مقاله (1.73 M)
نوع مقاله: Articles
شناسه دیجیتال (DOI): 10.30495/ijc.2022.1948621.1904
نویسندگان
Leena Vinolia Thaninki1، 2؛ Arputharaj Samson Nesaraj* 1، 3؛ Manasai Arunkumar1
1a) Department of Applied Chemistry, Karunya Institute of Technology and Sciences (Deemed to be University), Karunya Nagar, Coimbatore - 641114, Tamil Nadu, India
2Department of Chemistry, CMR Technical Campus, Kandlakoya, Hyderabad – 501 401, Telengana, India.
3Department of Chemistry, Kalasalingam Academy of Research and Education (Deemed to be University), Krishnankoil – 626126, Tamil Nadu, India.
چکیده
In this study, we discuss the wet chemical synthesis and experimental analysis of zinc doped Gd2O3(Gd2-xZnxO3-δ) nanoparticles where, x=0, 0.1, 0.2, 0.3, 0.4, and 0.5. The cubic crystalline structure is derived from XRD results and the existence of metal-oxide bond has been confirmed from FTIR studies. According to SEM and PSA analysis, the produced nanoparticles are found to be of nano size. The EDX data verified the presence of Gd, Zn, and O in the samples. Based on UV-visible spectroscopy, the band gap and λmax values were computed. In an aqueous medium and under UV light irradiation, the photodegradation of Rhodamine B over Zn doped Gd2O3 nanoparticles was studied. It was observed that Gd1.50Zn0.50O3-δ has exhibited 82% of photo-degradation of the dye solution which further increased to 96% because of increasing the catalyst loading. The effect of pH and the concentration of the dye are also reported. According to the kinetic analysis, the photocatalysis process followed a pseudo-first-order kinetic model. A radical scavenger technique was used to further examine and identify the function of photoactive species.

تازه های تحقیق
  • Gd2-xZnxO3-δ (where x= where x=0, 0.1, 0.2, 0.3, 0.4 and 0.5) nanoparticles were prepared by simple one pot wet chemical precipitation method.
  • Their physical characteristics were analyzed by XRD, FTIR, particle size analysis, SEM, EDAX, UV and PL studies.
  • The photocatalytic degradation properties of Rhodamine B dye using                           Gd2-xZnxO3-δ based nanophotocatalysts were studied and reported.
  • It was observed that Gd50Zn0.50O3-δ has shown 82% degradation efficiency of the dye solution which was further increased to 96% with increase in the catalyst loading.
کلیدواژه‌ها
Co-precipitation method؛ Zn doped Gd2O3 catalysts؛ Photodegradation؛ Rhodamine B
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