Photocatalytic degradation studies of malachite green dye by hydrothermally synthesized Cobalt Vanadate nanoparticles

International Journal of Nano Dimension

مقاله 4، دوره 14، شماره 2، تیر 2023، صفحه 145-156   

نوع مقاله: Reasearch Paper

شناسه دیجیتال (DOI): 10.22034/ijnd.2022.1965246.2172

نویسندگان

Lakshmana Naik Ramavathu^{* 1}؛ Bala Narsaiah Tumma²؛ Ponniah Justin³

¹Department of Chemical Engineering, Rajiv Gandhi University of Knowledge Technologies, RK Valley, Kadapa-516330, India.

²Department of Chemical Engineering, JNTUACEA, Ananthapuramu-515002, India.

³Department of Chemistry, Rajiv Gandhi University of Knowledge Technologies, RK Valley, Kadapa-516330, India.

چکیده

Cobalt vanadate (Co₃V₂O₈) nanoparticles were prepared by a hydrothermal process using ammonia metavanadate and cobalt nitrate as precursors and calcined at 450 °C to obtain pure Co₃V₂O₈ nanoparticles. The sample was characterized by scanning electron microscopy, X-ray diffraction, Fourier transform infrared, and UV-visible diffuse reflectance spectroscopy. The characterization analysis confirmed variations in the structure, shape, functional group, and energy gap of Co₃V₂O₈ nanoparticles. Using the Tauc relationship, the energy band gap was determined by analyzing the Tauc curve. The nanoparticles obtained had an average size of 40 nm and found the zeta potential of the nanoparticles was -78 mV, indicating good dispersion and stability. The photocatalytic activity of Co₃V₂O₈ nanoparticles through the degradation of malachite green dye was investigated under UV light irradiation. According to the results, Co₃V₂O₈ nanoparticles showed a maximum removal efficiency of 89 percent in 60 minutes. It shows that synthesized Co₃V₂O₈ nanoparticles have a strong potential for application as a photocatalyst to degrade textile dyes in wastewater treatment rapidly.

کلیدواژه‌ها

Cobalt Vanadate؛ Degradation؛ Hydrothermal Synthesis؛ Malachite Green؛ Photocatalyst؛ Wastewater Treatment

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