Application Molecularly Imprinted Solid Phase Extraction Method for Analysis and Determination of Bentazon as a Toxic Herbicide in Water

Journal of Applied Chemical Research

دوره 16، شماره 4، دی 2022، صفحه 65-79   

نوع مقاله: Original Article

نویسندگان

Alireza Geramizadegan¹؛ Dadkhoda Ghazanfari¹؛ Aliasghar Amiri^{* 2}

¹Department of Chemistry, Faculty of Science, Kerman Branch, Islamic Azad University, Kerman, Iran

²Department of Applied Chemistry, Faculty of Science, Shiraz Branch, Islamic Azad University, Shiraz, Iran

چکیده

In  this  paper,  a  highly  selective  sample  cleanup  procedure  combining  molecular  imprinting  and 
solid phase extraction (MI-SPE) was developed for the isolation of toxic bentazon in surface water. 
The molecularly imprinted polymer (MIP) was prepared using bentazon as the template molecule, 
methacrylic acid as the functional monomer, and ethylene glycol dimethacrylate as the cross-linking 
monomer. The  bentazon  imprinted  polymer  was  used  as  a  selective  sorbent  for  the solid-phase 
extraction  of  bentazon  from  surface  water.  An  offline  MI-SPE  method  followed  by  highperformance liquid chromatography was also established. To evaluate the applicability of the MIP 
for separation and determination of bentazon by HPLC, general parameters for SPE including the 
number of  loading  solvents,  washing  solution  and  eluent, and  pH  of  the  sample  were  optimized 
following a step-by-step approach. The calibration curve was linear in the range of (0.05 to 0.6 µg L−1).  The  standard  deviation  of  (2.2  %)  and  detection  limit  of  the  method  (0.05  µg  L−1)  were 
obtained for sensor level response. It was shown that recoveries up to approximately 97.0 % from 
spiked surface water samples could be obtained.  It was demonstrated that the proposed MI-SPEHPLC method could be applied to the direct determination of bentazon in surface water.

کلیدواژه‌ها

Toxic Bentazon؛ Molecular imprinting؛ Solid phase extraction؛ determination. 

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