Nano-cellulose-OSnCl4-x: Green and natural-based renewable nanocatalyst for one-pot synthesis of 2-amino-3-phenylsulfonyl-4H-pyran derivatives

Shafe-Mehrabadi, Sayed Rasul; Sadeghi, Bahareh; Mosslemin, Mohammad Hossein; Hashemian, Saeedeh

doi:10.30495/ijc.2022.1958448.1933

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	Nano-cellulose-OSnCl4-x: Green and natural-based renewable nanocatalyst for one-pot synthesis of 2-amino-3-phenylsulfonyl-4H-pyran derivatives
Iranian Journal of Catalysis
دوره 12، شماره 4، اسفند 2022، صفحه 407-416 اصل مقاله (1.07 M)
نوع مقاله: Articles
شناسه دیجیتال (DOI): 10.30495/ijc.2022.1958448.1933
نویسندگان
Sayed Rasul Shafe-Mehrabadi¹؛ Bahareh Sadeghi^* ²؛ Mohammad Hossein Mosslemin¹؛ Saeedeh Hashemian¹
¹Department of Chemistry, Yazd Branch, Islamic Azad University, Yazd, Iran
²Department of Chemistry, Central Tehran Branch, Islamic Azad University, Tehran, Iran
چکیده
A highly efficient, eco-friendly procedure has been proposed for the synthesis of 2-amino-3-phenylsulfonyl-4H-pyran derivatives via nano-cellulose-OSnCl_4-x catalyst prepared from cotton as support treated with tin tetrachloride (SnCl₄). This catalyst is characterized by FT-IR, FESEM, TEM, TGA, and EDX. The TEM results confirmed the size of the nano-cellulose-OSnCl_4-x catalyst was below 30 nm. The efficiency of this solid acid catalyst was investigated in one-pot, three-component condensation reactions with aromatic aldehydes, dimedone, and phenylsulfonylacetonitrile under reflux conditions. As a result, 2-amino-3-phenylsulfonyl-4H-pyran derivatives were produced under facile conditions in high yield (84-95%) and high rate (30-50 min) using nano-cellulose-OSnCl_4-x as a recyclable catalyst.
تازه های تحقیق
Preparation, characterization and application of nano-cellulose-OSnCl_4-x as a green and natural-based nanocatalyst Nano-cellulose-OSnCl_4-x as a renewable nanocatalyst for one-pot synthesis of 2-amino-3-phenylsulfonyl-4H-pyran derivatives Synthesis of new derivatives of 2-amino-7,8-dihydro-7,7-dimethyl-4-phenyl-3-(phenylsulfonyl)-4H-chromen-5(6H)-one Prominent among the advantages of this method are working simplicity, mild reaction condition, short reaction times, higher yields, and environmental friendliness
کلیدواژه‌ها
Phenylsulfonylacetonitrile؛ pyran derivatives؛ dimedone؛ green chemistry؛ nano-cellulose-OSnCl4-x

مراجع
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Nano-cellulose-OSnCl4-x: Green and natural-based renewable nanocatalyst for one-pot synthesis of 2-amino-3-phenylsulfonyl-4H-pyran derivatives