Synthesis of SO4/ZrO2 Catalyst and its Application in the Conversion of Ethanol to Diethyl Ether

Iranian Journal of Catalysis

دوره 12، شماره 4، اسفند 2022، صفحه 439-450   

نوع مقاله: Articles

شناسه دیجیتال (DOI): 10.30495/ijc.2022.1963196.1948

نویسندگان

Rena Septiyaningrum¹؛ Amalia Kurnia Amin²؛ Wega Trisunaryanti¹؛ Karna Wijaya^{* 1}

¹Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Yogyakarta 55281, Indonesia

²Research Center for Chemistry, National Research and Innovation Agency, South Tangerang 15314, Indonesia

چکیده

SO₄/ZrO₂ heterogeneous acid catalyst was prepared by wet impregnation method from ZrO₂ precursor involved variations in H₂SO₄ concentration (0.5; 1.0; 1.5 M) and calcination temperature (400, 500, 600 ℃) to yield catalyst with the highest acidity value. The catalysts produced were characterized using Fourier Transform Infrared (FTIR) spectrometer, X-Ray Diffractometer (XRD), Scanning Electron Microscope-Energy Dispersive X-Ray (SEM-EDX), Thermogravimetry and Differential Scanning Calorimeter (TGA-DSC), Gas Sorption Analyzer (GSA), and acidity test using the gravimetric method with ammonia vapor. The catalyst used to observe activity and selectivity in the dehydration reaction of ethanol to diethyl ether (DEE) was SO₄/ZrO₂ catalyst with the highest total acidity. The liquid product from the dehydration of ethanol was analyzed using Gas Chromatography (GC). The ZS‐1.5‐500 catalyst showed the best activity and selectivity in the dehydration reaction of ethanol to DEE at a temperature of 225 ℃, yielding 49.85% (w/w) ethanol conversion and a 1.62% DEE selectivity.

کلیدواژه‌ها

Ethanol dehydration؛ Diethyl ether؛ Optimization؛ Catalysts؛ Sulfated zirconia

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