The most important parameters that affect the photocatalytic activity of ZnO nanostructures against organic dyes: A Review

Iranian Journal of Catalysis

مقاله 1، دوره 13، شماره 1، خرداد 2023، صفحه 1-21   

نوع مقاله: Reviews

شناسه دیجیتال (DOI): 10.30495/ijc.2023.1969439.1966

نویسندگان

Marwa Jawad Kadhim^{* 1}؛ Mazin Auny Mahdi^{* 1}؛ Abbas Mohammed Selman²؛ Salwan Kamal Jamel Al-Ani³؛ Jalal Jabar Hassan¹؛ Naser Mohammed Ahmed⁴

¹Department of Physics, College of Science, University of Basrah, Basrah, Iraq

²Department of Pharmacognosy and Medicinal plants, Faculty of Pharmacy, University of Kufa, Najaf, Iraq.

³Department of Physics, College of Science, Al-Mustansiriya University, Baghdad, Iraq

⁴School of Physics, Universiti Sains Malaysia, Gelugor, Penang, Malaysia

چکیده

Organic dyes are among the main sources of water pollution that cause serious health problems for living organisms. Removing dye pollution from water sources is important because of its high toxicity, so it has attracted the interest of researchers. Heterogeneous photocatalysis based on ZnO is one of the most important methods of pollution treatment. The purpose of this review is to summarize the use of ZnO nanostructure and ZnO modified as photocatalysts. The studied mechanism of dye photocatalytic activity and the most important factors affecting the photocatalytic process are discussed. The major effective parameters associated with the surface and morphology to look upon for the efficient photodegradation of organic pollution are structural and average particle size, surface area, band gap crystalline structure, surface density, and porosity. The photodegradation reactions depend on the state of ionization as well as on the surface charge of the photocatalyst and organic dye because pH will determine the charge of the catalyst according to the medium. On the other hand, the calcination temperature was increased throughout the work to break down the pores, which reduces the surface area of the synthesis photocatalyst. The type of dye has an important influence on the success of the photocatalytic process.

کلیدواژه‌ها

ZnO؛ Photocatalytic activity؛ Organic dyes؛ Photodegradation

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