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Khalaf, Hussein, El-Baki, Randa. (1402). Effectiveness of Ceria and Stania Nanoparticles in Photodegradation Tenoxicam Antibiotics Using UV-H2O2. نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 13(3), 285-297. doi: 10.30495/ijc.2023.1985433.2006
Hussein Abdel-Fattah Khalaf; Randa Fouad Abd El-Baki. "Effectiveness of Ceria and Stania Nanoparticles in Photodegradation Tenoxicam Antibiotics Using UV-H2O2". نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 13, 3, 1402, 285-297. doi: 10.30495/ijc.2023.1985433.2006
Khalaf, Hussein, El-Baki, Randa. (1402). 'Effectiveness of Ceria and Stania Nanoparticles in Photodegradation Tenoxicam Antibiotics Using UV-H2O2', نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 13(3), pp. 285-297. doi: 10.30495/ijc.2023.1985433.2006
Khalaf, Hussein, El-Baki, Randa. Effectiveness of Ceria and Stania Nanoparticles in Photodegradation Tenoxicam Antibiotics Using UV-H2O2. نشریه علمی پژوهشی دانشگاه آزاد اسلامی, 1402; 13(3): 285-297. doi: 10.30495/ijc.2023.1985433.2006

Effectiveness of Ceria and Stania Nanoparticles in Photodegradation Tenoxicam Antibiotics Using UV-H2O2

Iranian Journal of Catalysis
مقاله 3، دوره 13، شماره 3، آذر 2023، صفحه 285-297    اصل مقاله (1007.65 K)
نوع مقاله: Articles
شناسه دیجیتال (DOI): 10.30495/ijc.2023.1985433.2006
نویسندگان
Hussein Abdel-Fattah Khalaf* 1؛ Randa Fouad Abd El-Baki2
1Chemistry department, Faculty of Science, Damanhour University, Damanhour, Egypt
2Chemistry department, Faculty of Science, New Valley University, El-Kharja, 72511, Egypt
چکیده
Both metal oxides, ceria (CeO2) and stania (SnO2) are prepared by precipitation technique using ammonia solution (1:1) and characterized by thermogravimetric analysis (TGA), x-ray powder diffraction (XRD), transmission electron microscope (TEM), nitrogen adsorption-desorption (for the specific surface area determination, SBET) and used in the photodegradation of Tenoxicam (TEN) antibiotics by using ultraviolet irradiation in presence of hydrogen peroxide. The obtained results showed that ceria and stania have a comparable surface area of 12 and 11 m2 g-1, respectively, and the crystallite size measured by XRD was found to be 44 and 18 nm for ceria and stania, respectively. Also, the results show that by increasing the exposure time, the amount of degraded antibiotic was increased. Data obtained show that both oxides, ceria, and stania can be used effectively as catalysts in the photodegrading process as photocatalysts. Stania is faster than ceria to degrade TEN antibiotics. Ceria needs more time than stania to degrade the drug at 100%, in which the TEN is fully degraded in the presence of stania and H2O2 at 40 minutes under certain conditions.

تازه های تحقیق
  • This study is considered new of its kind in terms of the removal of the antibiotic TEN from aqueous solutions, which showed impressive results in terms of the percentage of removal in record time.
  • Both ceria and stania were prepared using a precipitation technique and characterized using various analysis techniques.
  • The surface area of both ceria and stania was found to be comparable at 12 and 11 m2 g-1, respectively.
  • The crystallite size of ceria was measured to be 44 nm, while stania had a smaller crystallite size of 18 nm.
  • Stania was found to be faster than ceria in degrading TEN antibiotics, with TEN fully degrading in the presence of stania and H2O2 within 40 minutes under certain conditions.
کلیدواژه‌ها
Adsorption؛ Photocatalyst؛ Kinetics؛ Cerium oxide؛ Tin oxide
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