Copper concentration using micelle-mediated extraction in real samples

Journal of the Iranian Chemical Research

مقاله 1، دوره 1، شماره 1، دی 2008، صفحه 1-10   

نویسندگان

Farshid Ahmadi^{* 1}؛ Azadeh Khanmohammadi²؛ Ziba Tavakoli¹؛ Jamshid Jafarpour¹

¹Chemistry Department, Islamic Azad University, Gachsaran Branch, Gachsaran, Iran

²Young Researchers Club, Islamic Azad University, Gachsaran Branch, Gachsaran, Iran

چکیده

A simple and sensitive method is described for the pre-concentration by cloud point extraction followed by atomic absorption spectrometric determination of copper ion in real samples. At a solution pH of 5.5, 5, 5-diphenylimidazolidine-2, 4-dione (phenytoin) (DFID) and TritonX-114 were used as hydrophobic ligand and non-ionic surfactant. The adopted concentrations for DFID, Triton X-114 and HNO₃, bath temperature, centrifuge rate and time were optimized. Detection limits (3SDb/m) of 1.7 ng mL^-1 along with enrichment factors of 35 for these ions were achieved. The proposed procedure was applied to the analysis of real samples.

کلیدواژه‌ها

Cloud point extraction؛ Copper؛ Triton X-114؛ Flame atomic absorption spectrometry

مراجع

[1] M. Akhond, M. Ghaedi, J. Tashkhourian, Bull. Korean Chem. Soc. 26 (2005) 882.
[2] M. Ghaedi, M.K. Amini, A. Rafi, S. Gharaghani, A. Shokrolahi, Ann. Chim. 95 (2005) 457.
[3] M. Ghaedi, F. Ahmadi, H. Karimi, S. Gharaghani, J. Korean Chem. Soc. 50 (2006) 23.
[4] M. Ghaedi, M.R. Fathi, F. Marahel, F. Ahmadi, Fresen. Environ. Bull. 14 (2005) 1158.
[5] M. Ghaedi, E. Asadpour, A. Vafaie, Bull. Chem. Soc. Japan 79 (2006) 432.
[6] M. Ghaedi, A. Shokrollahi, Fresen. Environ. Bull. 151373 (2006)1373.
[7] M. Ghaedi, Spectrochim. Acta Part A 63 (2006)193.
[8] M. Ghaedi, E. Asadpour, A. Vafaie, Spectrochim. Acta. Part A 182 (2006) 182.
[9] F.H. Quina, W.L. Hinze, Ind. Eng. Chem. Res. 38 (1999) 4150.
[10] E. Pramauro, A.B. Prevot, Pure Appl. Chem. 67 (1995) 551.
[11] L.J. Cline Love, J.G. Habarta, J.G. Dorsey, Anal. Chem. 56 (1984) 1132.
[12] C.D. Stalikas, Trends Anal. Chem. 21 (2002) 343.
[13] W.L. Hinze, E. Pramauro, Crit. Rev. Anal. Chem. 24 (1993) 133.
[14] A. Sanz-Medel, M.R. Fernandez de la Campa, E.B. Gonzalez, M.L. Fernandez-Sanchez, Spectrochim. Acta. Part B 54 (1999) 251.
[15] A.E. Fernandez, Z.S. Ferrera, J.J.S. Rodriguez, Analyst 124 (1999) 487.
[16] R. Carabias-Martinez, E. Rodriguez-Gonzalo, J. Dominguez-Alvarez, Anal. Chem. 71 (1999) 2468.
[17] M.F. Silva, L. Fernandez, R. Olsina, D. Stacchiola, Anal.Chim. Acta 342 (1997) 229.
[18] S. Igarashi, K. Endo, Anal. Chim. Acta 320 (1996) 133.
[19] J. Li, P. Liang, T.Q. Shi, H.B. Lu, At. Spectrosc. 24 (2003) 169.
[20] S.A. Kulichenko, V.O. Doroschuk, S.O. Lelyushok, Talanta 59 (2003) 767.
[21] C. Garcia Pinto, J.L. Perez Pavon, B. Moreno Cordero, E. Romero Beato, S. Garcia Sanchez, J. Anal. At. Spectrom. 11 (1996) 37.
[22] J.C. Chen, K.C. Teo, Anal. Chim. Acta 450 (2001) 215.
[23] J.L. Manzoori, A.B.Tabrizi, Anal. Chim. Acta. 470 (2002) 215.
[24] M. Ghaedi, F. Ahmadi, Z. Tavakoli, M. Montazerozohori, A. Khanmohammadi, M. Soylak, J. Hazard. Mater. 152 (2008) 1258.
[25] T. Saitoh, W.L. Hinze, Anal. Chem. 63 (1991) 2520.
[26] B. Froschl, G. Stangl, R. Niessner, Freseniu J. Anal. Chem. 22 (1997) 357.
[27] A.E. Fernández, Z.S. Ferrera, J.J. Santana Rodriguez, Quim. Analys. 16 (1997) 283.
[28] C. Mahugo Santana, Z.S. Ferrera, J.J. Santana Rodriguez, Analyst 127 (2002) 1031.
[29] A.E. Fernández, Z.S. Ferrera, J.J. Santana Rodriguez, Anal. Chim. Acta 358 (1998) 145.
[30] A.E. Fernández, Z.S. Ferrera, J.J. Santana Rodriguez, Analyst 24 (1999) 487.