4-Chloro-3,5-dioxaphosphacyclohepta[2,1-;3,4-']dinaphthalene (BINOL-PCl) as a Bulky and Efficient Reagent for the Transformation of Symmetric and Asymmetric Benzoins to Corresponding Benziles

Journal of the Iranian Chemical Research

مقاله 7، دوره 4، شماره 1، خرداد 2011، صفحه 51-57   

نویسندگان

Nader Noroozi Pesyan^{* 1}؛ Mahnaz Saraei²؛ Bakhshali Massoumi²؛ Maryam Sarbazi²

¹Department of Chemistry, Faculty of Science, Urmia University, 57159, Urmia, Iran

²Department of Chemistry, Tabriz Payam-e-noor University, Tabriz, Iran

چکیده

4-Chloro-3,5-dioxaphosphacyclohepta[2,1-;3,4-']dinaphthalene (BINOL-PCl) was found to be an efficient, bulky and selective reagent for the transformation of symmetric and asymmetric benzoins to the corresponding benziles at 0 °C to room temperature under nitrogen atmosphere in good yield.

کلیدواژه‌ها

4-Chloro-3,5-dioxaphosphacyclohepta[2,1-؛ 3,4-']dinaphthalene؛ Transformation reagent؛ Benzoin؛ Benzil

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