conformational properties and the anomeric effect study of phosphinanes

Journal of Chemical Reactivity and Synthesis

مقاله 4، دوره 4، شماره 2، آذر 2014، صفحه 25-32   

نوع مقاله: Research Article

نویسندگان

Javad Azizian^{* 1}؛ Mahdieh Entezari²؛ Hossein Anaraki Ardakani²؛ Shahab Zomorodbakhsh²

¹Department of chemistry, Science and Reaserch branch, Islamic azad university, Tehran, Iran

²Department of chemist r,y Mahshahr branch, Islamic azad university, Mahshahr, Iran

چکیده

Ab initio HF/6-31G* Methode was employed to calculate the bond length in 2- phosphinanes when electronegative groups was at C-2 tend axial and equatorial positions. The magnitude of the anomeric effect depends on the nature of the substituent, the effect of the substituent can be seen by comparing the bond length in 2-chloro and 2- boromo substituented phosphinanes. The effect of anomeric effect have been effected on the bond length in 2-phosphinanes.

کلیدواژه‌ها

anomeric effect؛ 2- phosphinane؛ bond length؛ axial and equatorial position؛ Ab initio calculations

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