Fast Removal of Citalopram Drug from Waste Water Using Magnetic Nanoparticles Modified with Sodium Dodecyl Sulfate Followed by UV-Spectrometry

Journal of Chemical Health Risks

مقاله 5، دوره 3، شماره 4، اسفند 2013   

شناسه دیجیتال (DOI): 10.22034/jchr.2018.544046

نویسندگان

M. Khoeini Sharifabadi^* ؛ M. Saber Tehrani؛ A. Mehdinia؛ P. Abroomand Azar؛ S. Waqif Husain

چکیده

A simple and sensitive, solid-phase extraction method for the removal of Citalopram drug from waste water has been developed by using magnetic nanoparticles modified with surfactant sodium dodecyl sulfate. These magnetic nanoparticles have shown great adsorptive tendency towards Citalopram drug. The effect of different parameters influencing the extraction efficiency of this drug were investigated and optimized including the pH, amount of the surfactant, contact time and temperature. The extracts were analyzed by ultraviolet spectrophotometry at 239nm. Under these conditions, the related standard deviation (RSD %) of the method at two concentrations (5 and 50µg.mL-1) was in the range of (3.14–3.75) % (n = 8). The calibration curve was linear in the range of 2-100 µg.mL-1 of Citalopram drug with a correlation coefficient of >0.99.

کلیدواژه‌ها

Fe3O4 magnetic nanoparticles؛ Citalopram hydrobromide؛ waste water؛ Solid-phase micro extraction؛ UV- spectrometry

مراجع

1. Baumann P., Rochat B., 1995. Comparative Pharmacokinetics of selective serotonin reuptake inhibitors: a look behind the mirror. International Clinical Psychopharmacology.10: 15-21.
2. Mourilhe P., Stokes P.E., 1998. Risk and benefits of selective reuptake inhibitors in the treatment of depression.Drug Safety. 18:57-82.
3. Kasper S., Hoflich G., Scholl H.P., Moller H.J., 1994. Safety and antidepressant efficacy of Selective serotonin reuptake inhibitors. JournalofClinical Pharmacology. 9:1-12.
4. Worm K., Dragsholt C., Simonsen K., Kringsholm B., 1998. Citalopram concentrations in samples from autopsies and living persons. International Journal of Legal Medicin. 111:188-190.
5. Ostrom M., Eriksson A., Thorson J., Spigest O., 1996. Fatal overdose with citalopram.Lancet.348:339-340.
6. Howland R.H., 2011. A critical evaluation of the Cardiac Toxicity of Citalopram.Psychology&Society Journal. 49:13-16.
7. Cooke M.J., Waring W.S., 2013. Citalopram and cardiac Toxicity.Eur. Journal of Clinical Pharmacology.69:755-760.
8. Singer P.P., Jones G.R., 1997. An uncommon fatality due to moclobemide and paroxetine.Journal of Analytical Toxicology.21:518-520.
9. Neuvonen P.J., PohjolaSintonen S., Tacke U., Vuori E., 1993. Five fatal cases of Serotonin Syndrome after moclobemide-citalopram or moclobemid clomipramine over dose. Lancet. 342:1419-1420.
10. Sternbach H., 1991. The serotonin syndrome.American Journal of Psychiatry. 148:703-713.
11. Ferslew K.E., Hagardorn A.N., Harlan G.C., Mccor Mick W.F., 1998. A fatal drug interaction between clozapine and fluoxetine. Journal of Forensic Sciences. 43:1082-1085.
12. Mak S.Y., Chen D.H., 2004. Fast adsorption of methylene blue on polyacrylic acidââ‚‌“ bound iron oxide magnetic nano particles. Dyes and Pigments. 6:93-98.
13. Macek J., Ptacek P., Klima J., 2001. Rapid determination of citalopram in human plasma by High performance liquid chromatography.Journal of Chromatography B. 755: 279-285.
14. Pistos C., Panderi I., 2004. Liquid chromatography positive ion electrospray mass spectrometry method for the quantification of citalopram in human plasma. Journal of Chromatography B. 810: 235-244.
15. Kristoffersen L., Bugge A., Lundanes E., Slordal L., 1999. Simultaneous determination of Citalopram fluoxetine, paroxetine and their metabolites in plasma and whole blood by high performance liquid chromatography with ultraviolet and fluorescence detection. Journal of Chromatography B. 734: 229-246.
16. Molander P., Thomassen A., Kristoffersen L., Greibrokk T., Lundanes E., 2001. Simultaneous determination of citalopram, fluxetine, paroxetine and their metabolites in plasma by temperature programmed packed capillary liquid chromatography with onââ‚‌“column focusing of large injection volumes. Journal of Chromatography B. 766: 71-87.
17. Juan H., Zhiling Z., Huande L., 2005. Simultaneous determination of fluoxetine, citalopram, paroxetine, venlafaxine in plasma by high performance liquid chromatography-electro spray ionization mass spectrometry. Journal of Chromatography B. 820: 33-39.
18. Meng Q.H., Gauthier D., 2005.Simultaneous analysis of citalopram and desmethyl citalopram by liquid chromatography with fluorescence detection after solid phase extraction.Clinical BiochemistryJournal .38: 282-285.
19. Wille S.M.R., Maudens, K.E., Van-Peteghem C.H., 2005. Development of a solid phase extraction for13 (new) generation antidepressants and their active metabolites for gas chromatographicââ‚‌“mass spectrometric analysis. Journal of Chromatography A.1098:19-29.
20. BerzasNevado J.J., VillasenorLierena M.J., GuiberteauCabanillas C., Rodriquez Robledo V., 2006. Screening of citalopram, fluoxetine and their metabolites in human urine samples by gas chromatographyââ‚‌“mass spectrometry. A global robustness/ruggedness study. Journal of Chromatography A.1123:130-133.
21. Bagheri H., Khalilian F., Babanezhad E., Eshaghi A., 2008. Solvent microextraction with back Extraction combined with liquid chromatographyââ‚‌“fluorescence detection for the determination of citalopram in human plasma. Analytical ChimicalActa. 610: 211-216.
22. Parham H., Pourreza N., Rahbar N., 2009. Solid phase extraction of lead and cadmium using Solid sulfur as a new metal extractor prior to determination by flame atomic absorption spectrometry. Journal of Hazardous Materials .163:588-592.
23. Ngeontae W., Aeungmaitrepirom W., Tuntulani T., 2007. Modified silica gel with amino thioamidoanthraquinone for solid phase extraction and pre- concentration of Pb(II), Cu(II), Ni(II), Co(II) and Cd(II). Talanta. 71:1075-1082.
24. Maier M., Fritz H., Gerster M., Schewitz J., 1998. Quantitative analysis of modified antisense oligonucleotides in biological fluids using cationic nanoparticles for solid phase extraction.Journal of Analytical Chemistry. 70: 2197-2204.
25. Song Y., Zhao S., Tchounwou P.B., Liu Y.M., 2007. A nanoparticle based solid phase extraction method for liquid chromatographyââ‚‌“electrospray ionization-tandem mass spectrometric analysis. Journal of Chromatography A.1166: 79-84.
26. Sun Y.K., Ma M., Zhang Y., Gu N., 2004. Synthesis of nanometer-size magnemite particles From Magnetite.Colloids and Surfaces A. 245:15-19.
27. Jing T., Du H., Dai Q., Xia H., Niu J., Hao Q., Mei S., Zhou Y., 2010. Magnetic molecularly Imprinted nanoparticles for recognition of lysozyme. Biosensors& Bioelectronics. 26: 301-306.
28. Chen L.G., Liu, J., Zeng, Q.L., Wang, H., Yu, A.M., Zhang, A.M., 2009. Preparation of magnetic molecularly imprinted antibiotics from egg and tissue samples. Journal of Chromatography A.1216: 3710-3719.
29. Mehdinia A., BaradaranKayyal T., Jabbari A., OvaisazizZanjani M., Ziaei E., 2013. Magnetic molecularly imprinted nanoparticles based on grafting polymerization for selective detection of 4-nitrophenol in aqueous sample. Journal of Chromatography A.1283:82-88.
30. Faraji M., Yamini Y., Rezaee M., 2010. Extraction of trace amounts of mercury with sodium dodecyl sulphateââ‚‌“coated magnetite nanoparticles and its determination by flow injection inductively coupled plasmaââ‚‌“optical emission spectrometry.Talanta .81: 831-836.
31. Lu A.H., Salabas E.L., Schuth F., 2007. Magnetic nanoparticles: synthesis, protection, functionalization and application.Angewandte Chemie International England .46:1222-1246.
32. Afkhami A., Saber-Tehrani M., Bagheri H., 2010. Simultaneous removal of heavy metal ions in waste waters samples using nanoââ‚‌“alumina modified with 2, 4 ââ‚‌“ dinitrophenyl hydrazine. Journal of Hazardous Materials. 181: 836-844.
33. Faraji M., Yamini Y., Saleh A., Rezaee M., Ghambarian M., Hassani R., 2010. A nanoparticle-based solid phase extraction procedure followed by flow injection inductively coupled plasma-optical emission spectrometry to determine some heavy metal ions in water samples. Analytical ChimicalActa .659:172-177.
34. Parham H., Rahba N., 2009. Solid phase extraction spectrophotometric determination of Salicylic acid using magnetic iron oxide nanoparticles as extractor. Journal of Pharmacutical and Biomedical Analysis. 50: 58-63.
35. Holsen T.M., Taylor E.R., Seo Y.C., Anderson P.R., 1991. Removal of sparingly soluble organic chemical from aqueous solutions with surfactantââ‚‌“coated ferrihydrite.Journal of Environmental Science and Technology. .25: 585-589.
36. Zhao X., Shi Y., Cai Y., Mou S., 2008. Cetyltrimethyl ammonium bromide coated magnetic nanoparticles for the preconcentration of phenolic compound from environmental water samples. Journal of Environmental Science and Technology. 42: 1201-1206.