Rapid oxidation of alcohols and trimethylsilyl and tetrahydropyranyl ethers with CrO3 in the presence of sulfonic acid functionalized ordered nanoporous Na+-montmorillonite

Iranian Journal of Catalysis

مقاله 1، دوره 4، شماره 1، خرداد 2014، صفحه 1-7   

نویسندگان

Farhad Shirini^{* 1}؛ Masoumeh Abedini²؛ Ahmad Nasiri Abkenar³؛ Bita Baghernejad³

¹Department of Chemistry, College of Science, University of Guilan, Rasht, 41335, Iran

²Department of Chemistry, College of Science, University of Guilan, Rasht, 41335, Iran.

³Department of Chemistry, School of Sciences, Payame Noor University (PNU), Iran, 19395-3697

چکیده

A mild, efficient and fast method for the oxidation of alcohols and trimethylsilyl and tetrahydropyranyl ethers to their corresponding carbonyl compounds using CrO₃ in the presence of sulfonic acid functionalized ordered nanoporous Na⁺-montmorillonite (SANM) and under solvent-free conditions is reported. All reactions were performed at room temperature in high to excellent yields. Ease of the preparation and handling of the catalyst, heterogeneous conditions, easy work-up of the products and high reaction rates are the main advantages of this method.

کلیدواژه‌ها

Na+-montmorillonite؛ CrO3؛ Alcohols؛ Trimethylsilyl ethers؛ Tetrahydropyranyl ethers؛ Oxidation reactions

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