Silica-bonded n-propyldiethylenetriamine sulfamic acid as a recyclable solid acid catalyst for the synthesis of coumarin and biscoumarin derivatives

Iranian Journal of Catalysis

مقاله 6، دوره 4، شماره 3، آذر 2014، صفحه 163-173   

نوع مقاله: Articles

نویسندگان

Khodabakhsh Niknam^{* 1}؛ Seyed Ahmad Sajadi²؛ Roghayeh Hosseini²؛ Mojtaba Baghernejad³

¹Department of Chemistry, Faculty of Sciences, Persian Gulf University, Bushehr 75169, Iran.

²Department of Chemistry, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran.

³Young Researchers and Elite Club, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran.

چکیده

Silica-bonded n-propyldiethylenetriamine sulfamic acid (SBPDSA) was found as an efficient solid acid for the synthesis of coumarins. Coumarin derivatives were obtained via the Pechmann condensation reaction of phenols and β-keto-esters at 80 oC under solvent-free conditions. Also, biscoumarins were obtained via the condensation of aldehydes and 4-hydroxycoumarin in water at reflux conditions. The heterogeneous solid acid showed much the same efficiency when used in consecutive reaction runs.

کلیدواژه‌ها

Silica-bonded n-propyldiethylenetriamine sulfamic acid؛ Coumarins؛ Pechmann reaction؛ Aromatic aldehydes؛ Biscoumarins؛ Solid acids؛ Catalyst

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